245011

Triruthenium dodecacarbonyl

99%

• 동의어(들): Ruthenium carbonyl, tri-Ruthenium dodecacarbonyl
• Linear Formula: Ru₃(CO)₁₂
• CAS Number: 15243-33-1
• Molecular Weight: 639.33
• EC Number: 239-287-4
• MDL number: MFCD00011209
• UNSPSC 코드: 12161600
• PubChem Substance ID: 24854727
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 99%
• 형태: crystals
• 반응 적합성: core: ruthenium; reaction type: C-H Activation; reagent type: catalyst
• SMILES string: [Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
• InChI: 1S/12CO.3Ru/c12*1-2;;;
• InChI key: NQZFAUXPNWSLBI-UHFFFAOYSA-N

설명

일반 설명

Atomic number of base material: 44 Ruthenium

애플리케이션

Carbonyl cluster precursor and H-transfer catalyst. Used in the reductive carbonylation of aromatic nitro compounds to carbamates. The phosphine-stabilized carbonyl cluster has been tethered to oxide supports. Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.

Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,ß-unsaturated ketones providing good yields of α-pyrones.

기타 정보

A Practical Procedure for Reduction of Primary, Secondary and Tertiary Amides to Amines

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H332
• 예방조치 성명서: P261 - P271 - P304 + P340 + P312
• Hazard Classifications: Acute Tox. 4 Inhalation
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges