309281

Iron(III) perchlorate hydrate

crystalline

• 동의어(들): Perchloric acid iron(III) salt hydrate
• Linear Formula: Fe(ClO₄)₃ · xH₂O
• CAS Number: 15201-61-3
• Molecular Weight: 354.20 (anhydrous basis)
• EC Number: 236-908-0
• MDL number: MFCD00149705
• UNSPSC 코드: 12352000
• PubChem Substance ID: 24858725
• NACRES: NA.22

속성

• 형태: crystalline
• Quality Level: 100
• 반응 적합성: reagent type: oxidant
• 불순물: <0.10% chloride
• 색상: yellow
• SMILES string: [Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• InChI: 1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
• InChI key: PFPIMAZLJXJVAN-UHFFFAOYSA-K

설명

애플리케이션

Catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization

Iron(III) perchlorate hydrate is a useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units and in photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution.

It can be used as a catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Fulleroxazolidines
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

안전성 정보

• 픽토그램: GHS03,GHS07
• 신호어: Danger
• 유해 및 위험 성명서: H272,H315,H319,H335
• 예방조치 성명서: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 5.1A - Strongly oxidizing hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable
• 개인 보호 장비: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges