349925

(+)-Chloromethyl menthyl ether

97%

• 실험식(Hill 표기법): C₁₁H₂₁ClO
• CAS Number: 103128-76-3
• Molecular Weight: 204.74
• MDL number: MFCD09039273
• UNSPSC 코드: 12352101
• PubChem Substance ID: 24861717
• NACRES: NA.22

속성

• Quality Level: 100
• 분석: 97%
• 형태: liquid
• 광학 활성: [α]24/D +181.0°, c = 2 in methylene chloride
• 광학 순도: ee: 98% (GLC)
• refractive index: n20/D 1.467 (lit.)
• bp: 72 °C/0.4 mmHg (lit.)
• density: 0.994 g/mL at 25 °C (lit.)
• 작용기: chloro; ether
• 저장 온도: −20°C
• SMILES string: CC(C)[C@H]1CC[C@H](C)C[C@@H]1OCCl
• InChI: 1S/C11H21ClO/c1-8(2)10-5-4-9(3)6-11(10)13-7-12/h8-11H,4-7H2,1-3H3/t9-,10+,11-/m0/s1
• InChI key: XOPLTFUYFXWFGB-AXFHLTTASA-N

설명

애플리케이션

(+)-Chloromethyl menthyl ether can be used:

• As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
• As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
• To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;⁵- C₂H₅)(PPh₃)COCH₃].

안전성 정보

• 픽토그램: GHS07
• 신호어: Warning
• 유해 및 위험 성명서: H315,H319,H335
• 예방조치 성명서: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 표적 기관: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point (°F): 224.6 °F - closed cup
• Flash Point (°C): 107 °C - closed cup
• 개인 보호 장비: Eyeshields, Gloves, type ABEK (EN14387) respirator filter