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애플리케이션
Magnesium bromide (MgBr2) can be used as a catalyst in:
- Acetylation and benzoylation of alcohols (primary and secondary) with acid anhydrides.
- In the synthesis of dihydropyrimidinones , trifluoromethylnaphthalenes , substituted 1,2,3,4 tetrahydropyrimidin-2-ones .
- In the preparation of Aldol derivatives by hydrogenation of Baylis-Hillman olefins.
- Deprotection of SEM (2-(Trimethylsilyl)ethoxymethyl) ether group.
Storage Class Code
11 - Combustible Solids
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
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시험 성적서(COA)
Lot/Batch Number
이미 열람한 고객
Magnesium bromide mediated highly diastereoselective heterogeneous hydrogenation of olefins
Bouzide, Abderrahim
Organic Letters, 4(8), 1347-1350 (2002)
Synthesis of trifluoromethylnaphthalenes
Mellor JM, et al.
Tetrahedron, 56(51), 10067-10074 (2000)
Magnesium bromide catalysed acylation of alcohols
Pansare SV, et al.
Synthetic Communications, 30(14), 2587-2592 (2000)
Novel deprotection of SEM ethers: a very mild and selective method using magnesium bromide
Vakalopoulos A and Hoffmann HMR
Organic Letters, 2(10), 1447-1450 (2000)
Efficient Magnesium Bromide-Catalyzed One-pot Synthesis of Substituted 1, 2, 3, 4-Tetrahydropyrimidin-2-ones Under Solvent-free Conditions
Salehi H and Guo Q-X
Chin. J. Chem., 23(1), 91-97 (2005)
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