모든 사진(2)
About This Item
Linear Formula:
C6H5CH2CH2CHO
CAS Number:
Molecular Weight:
134.18
Beilstein:
1071910
EC Number:
MDL number:
UNSPSC 코드:
12352100
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Grade
technical grade
Quality Level
분석
90%
양식
liquid
불순물
<5% 3-phenyl-1-propanol
refractive index
n20/D 1.523 (lit.)
bp
97-98 °C/12 mmHg (lit.)
density
1.019 g/mL at 25 °C (lit.)
작용기
aldehyde
phenyl
SMILES string
[H]C(=O)CCc1ccccc1
InChI
1S/C9H10O/c10-8-4-7-9-5-2-1-3-6-9/h1-3,5-6,8H,4,7H2
InChI key
YGCZTXZTJXYWCO-UHFFFAOYSA-N
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일반 설명
Hydrocinnamaldehyde is C=C double bond hydrogenated cinnamaldehyde. It has been synthesized by the selective hydrogenation of C=C double bond of cinnamaldehyde by various methods. Hydrocinnamaldehyde and nitromethane undergoes Henry reaction to form nitroaldols. The C1 and C3 position labelled with 13C of hydrocinnamaldehyde was subjected to mass spectrometry and the fragmentation pattern was elucidated.
애플리케이션
Hydrocinnamaldehyde may be used in the synthesis of the following:
- 2-Chloro hydrocinnamaldehyde by α-chlorination.
- Mixture of homopropargyl alcohols by kinetic resolution-allenylboration reactions.
- Mixture of syn- and anti-β-hydroxyallylsilanes by hydroboration of allenylsilane.
- (2S)-2-Hydroxy-4-phenylbutanenitrile by catalytic asymmetric cyanosilylation.
- Cinnamaldehyde by dehydrogenation reaction using Pd(TFA)2/4,5-diazafluorenone catalyst.
Storage Class Code
10 - Combustible liquids
WGK
WGK 2
Flash Point (°F)
203.0 °F - closed cup
Flash Point (°C)
95 °C - closed cup
개인 보호 장비
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
이미 열람한 고객
Influence of Preparation Modes on Pt-Ni/CNTs Catalysts Used in the Selective Hydrogenation of Cinnamaldehyde to Hydrocinnamaldehyde.
Li Y, et al
Catalysis Letters, 126(3-4), 280-285 (2008)
Ming Chen et al.
Organic letters, 13(8), 1992-1995 (2011-03-18)
The kinetic hydroboration of allenylsilane 5 with ((d)Ipc)(2)BH at -40 °C provides allylborane 9Z with ≥12:1 selectivity. When the hydroboration is performed at temperatures above -40 °C, 9Z isomerizes to the thermodynamically more stable allylborane 9E with >20:1 selectivity. Subsequent
Andy S Tsai et al.
Organic letters, 15(7), 1568-1571 (2013-03-15)
A chiral phosphoric acid catalyzed kinetic resolution/allenylboration of racemic allenylboronates with aldehydes is described. Allenylboration of aldehydes with 2.8 equiv of allenylboronate (±)-1 in the presence of 10 mol % of catalyst (R)-2 provided anti-homopropargyl alcohols 3 in 83-95% yield
Carbon nanofiber supported palladium catalyst for liquid-phase reactions: An active and selective catalyst for hydrogenation of cinnamaldehyde into hydrocinnamaldehyde.
Pham-Huu C, et al
J. Mol. Catal. A: Chem., 170(1), 155-163 (2001)
Tianning Diao et al.
Chemical science, 3, 887-891 (2012-06-13)
The direct α, β-dehydrogenation of aldehydes and ketones represents an efficient alternative to stepwise methods to prepare enal and enone products. Here, we describe a new Pd(TFA)(2)/4,5-diazafluorenone dehydrogenation catalyst that overcomes key limitations of previous catalyst systems. The scope includes
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