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Merck
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주요 문서

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414492

Sigma-Aldrich

2-(Tributylstannyl)thiophene

97%

동의어(들):

2-(Tributyltin)thiophene, 2-Thienyltributyltin, Tributyl(thiophen-2-yl)stannate, Tributyl-2-thienylstannane, Tributylthiophen-2-ylstannane

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About This Item

실험식(Hill 표기법):
C16H30SSn
CAS Number:
54663-78-4
Molecular Weight:
373.18
MDL number:
MFCD00192513
UNSPSC 코드:
12352103
PubChem Substance ID:
24865938
NACRES:
NA.22

Quality Level

100

분석

97%

형태

liquid

refractive index

n20/D 1.518 (lit.)

bp

155 °C/0.1 mmHg (lit.)

density

1.175 g/mL at 25 °C (lit.)

SMILES string

CCCC[Sn](CCCC)(CCCC)c1cccs1

InChI

1S/C4H3S.3C4H9.Sn/c1-2-4-5-3-1;3*1-3-4-2;/h1-3H;3*1,3-4H2,2H3;

InChI key

UKTDFYOZPFNQOQ-UHFFFAOYSA-N

애플리케이션

2-(Tributylstannyl)thiophene has been used to synthesize diphenylquinoxaline monomer for the electrochromism polymers. It can also be used as a reactant in Stille coupling reaction.

픽토그램

Skull and crossbonesHealth hazardEnvironment
GHS06,GHS08,GHS09

신호어

Danger

유해 및 위험 성명서

H301,H312,H315,H319,H360FD,H372,H410

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point (°F)

221.0 °F - closed cup

Flash Point (°C)

105 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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시험 성적서(COA)

Lot/Batch Number
MKCT3723
MKCR2557
MKCR7309
MKCK6797
MKCH4280

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2,5-Bis(thiophene) and 2,5-bis(ethylenedioxy-thiophene) (EDOT) derivatives of 3,6-diethoxy-1,4-benzoquinone (para isomers) were prepared by Stille coupling between the 2,5-dibromo-3,6-diethoxy-1,4-benzoquinone precursors and (n-Bu)3Sn-R (R = 2-thiophenyl or 3,4-ethylenedioxy-2-thiophenyl) reagents. In a parallel series of experiments 2,6-bis(thiophene) and 2,6-EDOT-3,5-diethoxy-1,4-benzoquinone (meta isomers) were synthesized by
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Synthetic Metals, 123(3), 425-433 (2001)
Two-dimensional structural motif in thienoacene semiconductors: Synthesis, structure, and properties of tetrathienoanthracene isomers.
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Chemistry of Materials, 20(7), 2484-2494 (2008)
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