439320
4-(Trifluoromethyl)phenylboronic acid
≥95.0%
동의어(들):
α,α,α-Trifluoro-p-tolylboronic acid, 4-(Trifluoromethyl)benzeneboronic acid, [p-(Trifluoromethyl)phenyl]boronic acid
로그인조직 및 계약 가격 보기
모든 사진(3)
About This Item
Linear Formula:
CF3C6H4B(OH)2
CAS Number:
Molecular Weight:
189.93
Beilstein:
3544189
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.22
추천 제품
분석
≥95.0%
mp
245-250 °C (lit.)
SMILES string
OB(O)c1ccc(cc1)C(F)(F)F
InChI
1S/C7H6BF3O2/c9-7(10,11)5-1-3-6(4-2-5)8(12)13/h1-4,12-13H
InChI key
ALMFIOZYDASRRC-UHFFFAOYSA-N
유사한 제품을 찾으십니까? 방문 제품 비교 안내
애플리케이션
4-(Trifluoromethyl)phenylboronic acid can be used as a reactant in:
It can also be used as a reactant to prepare:
- Site-selective Suzuki-Miyaura cross-coupling reactions.
- Palladium-catalyzed direct arylation reactions.
- Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence.
- Ruthenium catalyzed direct arylation.
- Ligand-free copper-catalyzed coupling reactions.
- Amination and conjugate addition reactions.
- Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.
- Rhodium-catalyzed asymmetric 1,4-addition reactions.
- Copper-catalyzed nitration reactions.
- Regioselective Suzuki-Miyaura coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulation.
- Palladium catalyzed allylation reaction with allyl alcohols.
- N-Arylation of imidazoles and amines in the presence of copper-exchanged fluorapatite as a catalyst.
It can also be used as a reactant to prepare:
- Thiazole derivatives for printable electronics.
- Terphenyl benzimidazoles as tubulin polymerization inhibitors.
- Aryl ketones by cross-coupling reaction with acid chlorides.
기타 정보
Contains varying amounts of anhydride
신호어
Warning
유해 및 위험 성명서
예방조치 성명서
Hazard Classifications
Acute Tox. 4 Oral
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
dust mask type N95 (US), Eyeshields, Gloves
시험 성적서(COA)
제품의 로트/배치 번호를 입력하여 시험 성적서(COA)을 검색하십시오. 로트 및 배치 번호는 제품 라벨에 있는 ‘로트’ 또는 ‘배치’라는 용어 뒤에서 찾을 수 있습니다.
이미 열람한 고객
Viktor O Iaroshenko et al.
Organic & biomolecular chemistry, 10(15), 2955-2959 (2012-03-10)
A facile synthetic approach for the synthesis of 1,8-naphthyridine-4(1H)-one derivatives via a catalyst free and Pd-supported tandem amination sequence is developed and described. In a case of aliphatic amines reaction proceeds in a catalyst free mode, however anilines demand Pd-supported
Efficient synthesis of arylated coumarins by site-selective Suzuki-Miyaura cross-coupling reactions of the bis(triflate) of 4-methyl-5,7-dihydroxy-coumarin
Eleya, N.; et al.
Synlett, 23, 223-226 (2012)
S Van Mierloo et al.
Magnetic resonance in chemistry : MRC, 50(5), 379-387 (2012-04-18)
Four 2,5-bis(5-aryl-3-hexylthiophen-2-yl)thiazolo[5,4-d]thiazole derivatives have been synthesized and thoroughly characterized. The extended aromatic core of the molecules was designed to enhance the charge transport characteristics, and solubilizing hexyl side chains were introduced on the thiophene subunits to enable possible integration of
Microwave-promoted cross-coupling of acid chlorides with arylboronic acids: a convenient method for preparing aromatic ketones
Viera Polackova, et al.
Tetrahedron, 62, 11675-11678 (2006)
Palladium(0)-catalyzed direct cross-coupling reaction of allyl alcohols with aryl- and vinyl-boronic acids
Hirokazu Tsukamoto, et al.
Chemical Communications (Cambridge, England), 1200-1201 (2004)
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