추천 제품
Quality Level
분석
97%
반응 적합성
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
refractive index
n20/D 1.533 (lit.)
bp
165 °C/12 mmHg (lit.)
density
1.054 g/mL at 25 °C (lit.)
작용기
phosphine
SMILES string
ClP(C1CCCCC1)C2CCCCC2
InChI
1S/C12H22ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
InChI key
AKJFBIZAEPTXIL-UHFFFAOYSA-N
애플리케이션
Chlorodicyclohexylphosphine can be used as a reactant in the synthesis of:
It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.
- 1,2-Bis(dicyclohexylphosphinoxy)ethane ligand by reacting with ethylene glycol in the presence of triethylamine via Michaelis−Arbuzov type rearrangements.
- 1,1,2,2-tetracyclohexyldiphosphine monosulfide ligand by treating with LiS.
It can be also used as a starting material for the preparation of some other ligands such as dicyclohexylphosphine oxide , phosphino substituted N-aryl pyrroles , di-tert-butyl((dicyclohexylphosphino)methyl)phosphine , dicyclohexylcyclopentylphosphine. These ligands are used in Pd-catalyzed cross-coupling reactions.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
보충제 위험성
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point (°F)
235.4 °F - closed cup
Flash Point (°C)
113 °C - closed cup
개인 보호 장비
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
이미 열람한 고객
Simon Doherty et al.
Nature protocols, 7(10), 1870-1883 (2012-09-29)
This protocol describes the synthesis of a representative example of the electron-rich biaryl-like KITPHOS class of monophosphine, 11-dicyclohexylphosphino-12-phenyl-9,10-dihydro-9,10-ethenoanthracene (H-KITPHOS). The bicyclic architecture of H-KITPHOS is constructed via [4+2] Diels-Alder cycloaddition between 1-(dicyclohexylphosphinoylethynyl)benzene and anthracene. H-KITPHOS monophosphine is prepared via an
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Zhang, et al.
Haematologica (2023)
Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris (cyclopentylphosphine)
Douglas TM, et al.
Chemistry?A European Journal , 14(3), 1004-1022 (2008)
Practical synthesis of new and highly efficient ligands for the Suzuki reaction of aryl chlorides
Zapf A, et al.
Chemical Communications (Cambridge, England), 19(1), 38-39 (2004)
A sulfur mimic of 1, 1-bis (diphenylphosphino) methane: a new ligand opens up
Sues PE, et al.
Chemical Communications (Cambridge, England), 50(36), 4707-4710 (2014)
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