추천 제품
Quality Level
분석
97%
refractive index
n20/D 1.478 (lit.)
bp
74 °C/19 mmHg (lit.)
density
0.942 g/mL at 25 °C (lit.)
작용기
hydroxyl
SMILES string
OC1(CCCCC1)C=C
InChI
1S/C8H14O/c1-2-8(9)6-4-3-5-7-8/h2,9H,1,3-7H2
InChI key
ZXKHOVDDJMJXQP-UHFFFAOYSA-N
일반 설명
1-Vinyl cyclohexanol, also known as 1-vinyl-1-cyclohexanol, is a tertiary allylic alcohol. It can be synthesized from cyclohexanone and vinyl chloride. It can undergo transition-metal-free tandem allylic borylation in the presence of B2pin [bis(pinacolato)diboron], Cs2CO3, THF and MeOH to yield triborated product. Pd-fullerite catalysts have been prepared which effectively catalyzes the hydrogenation of 1-ethynyl-1-cyclohexanol to 1-vinyl-1-cyclohexanol.
애플리케이션
1-Vinyl cyclohexanol may be used to synthesize:
- 1-vinyl-1-cyclohexene
- 1-vinyl-1-cyclohexylacrylate
- cyclohexylideneacetaldehyde
신호어
Warning
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
표적 기관
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point (°F)
158.0 °F - closed cup
Flash Point (°C)
70 °C - closed cup
개인 보호 장비
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
가장 최신 버전 중 하나를 선택하세요:
Dimerization of conjugated cyclodienes.
Canadian Journal of Chemistry, 45(9), 933-937 (1967)
Synthesis of spirocyclic butenolides by ring closing metathesis.
Tetrahedron, 63(22), 4648-4654 (2007)
One-pot rapid low-cost synthesis of Pd-fullerite catalysts.
Journal of Materials Chemistry, 18(40), 4808-4813 (2008)
Lewis Acid Promoted Oxidative Rearrangement of Tertiary Allylic Alcohols with the PhIO/TEMPO System.
Synlett, 12, 1785-1788 (2008)
Transition-Metal-Free Borylation of Allylic and Propargylic Alcohols.
Angewandte Chemie (International Edition in English), 128(13), 4375-4379 (2016)
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