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Merck
모든 사진(3)

주요 문서

75991

Sigma-Aldrich

Palladium on activated charcoal

greener alternative

moistened with water, 5% Pd basis (based on dry substance)

동의어(들):

Pd/C

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About This Item

Linear Formula:
Pd
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

양식

paste

품질

moistened with water

포함

~50% water as stabilizer

반응 적합성

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

환경친화적 대안 제품 특성

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

농도

5% Pd (based on dry substance)

환경친화적 대안 카테고리

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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일반 설명

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애플리케이션

Palladium on activated charcoal can be used as a heterogeneous catalyst:
  • To synthesize methyl esters via oxidative esterification of primary alcohols.
  • In the hydrogenation of phenol to cyclohexanone.
  • For carbonylation of iodoanilines with amines and trimethyl orthoformate to prepare quinazolinones.
  • In the hydrodehalogenation of aromatic halides to form arenes in aqueous media.

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)


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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Oxidative Esterification of Primary Alcohols with a Pd/Bi/Te Catalyst
Uozumi Y and Osako T
Synfacts, 10, 0108-0108 (2014)
Highly selective palladium supported catalyst for hydrogenation of phenol in aqueous phase
Perez Y, et al.
Catalysis Communications, 12, 1071-1074 (2011)
Pd/C as an efficient heterogeneous catalyst for carbonylative four-component synthesis of 4 (3 H)-quinazolinones
Natte K, et al.
Catalysis Science & Technology, 5, 4474-4480 (2015)
Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure.
Xia C
Catalysis Communications, 5(8), 383-386 (2004)
Development of GSKDevelopment of GSK's reagent guides ? embedding sustainability into reagent selections reagent guides ? embedding sustainability into reagent selection.
Adams JP, et al.
Green Chemistry, 15, 1542-1549 (2013)

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