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일반 설명
Azobisisobutyronitrile (AIBN) is an azo-compound and is widely used as a free radical initiator. This compound has labile carbon-nitrogen covalent bond which undergoes homolytic scission under thermal, chemical or photochemical conditions producing free radicals. They are useful in many reactions like halogenation, polymerisation of vinyl monomers, grafting reactions, curing of rubbers and unsaturated polymers and cross-linking of polyolefins.
애플리케이션
- Used as an initiator in the synthesis of highly cross-linked Poly(divinylbenzene) (PDVB) polymers.
- Used as an initiator in the polymerization process of 2-hydroxyethyl methacrylate (HEMA).
특징 및 장점
Decomposes unimolecularly at good rates without much variation from one solvent to another.
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
표적 기관
Respiratory system
보충제 위험성
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point (°F)
1.4 °F
Flash Point (°C)
-17 °C
이미 열람한 고객
Biomaterials based on 2-hydroxyethyl methacrylate: the influence of the initiator type
Rev. Roum. Chim., 56(5), 537-543 (2011)
Synthesis of highly cross-linked polymers in supercritical carbon dioxide by heterogeneous polymerization.
Macromolecules, 32(7), 2156-2166 (1999)
Initiator efficiency in radical polymerization
Journal of Polymer Science, 14(74), 214-217 (1954)
Selected radical azoinitiators in the synthesis of solvent-borne acrylic pressure-sensitive adhesives
Chemistry and Chemical Technology, 3(2), 101-106 (2009)
International journal of pharmaceutics, 428(1-2), 134-142 (2012-03-10)
In the current study, poly lactic acid (PLA) modified hollow crosslinked poly(hydroxyethyl methacrylate) (PHEMA) microspheres have been prepared, in order to obtain a stimulus-responsive, biocompatible carrier with sustained drug release properties. The synthetical process consisted of the preparation of poly(methacrylic
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