81080
Chloroplatinic acid hydrate
~38% Pt basis
동의어(들):
Hexachloroplatinic(IV) acid hydrate, Hydrogen hexachloroplatinate(IV) hydrate, Platinic chloride hydrate
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모든 사진(1)
About This Item
Linear Formula:
H2PtCl6 · xH2O
CAS Number:
Molecular Weight:
409.81 (anhydrous basis)
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22
추천 제품
Quality Level
양식
powder
반응 적합성
core: platinum
reagent type: catalyst
농도
~38% Pt
mp
60 °C (lit.)
density
2.43 g/mL at 25 °C (lit.)
SMILES string
O.Cl.Cl.Cl[Pt](Cl)(Cl)Cl
InChI
1S/6ClH.H2O.Pt/h6*1H;1H2;/q;;;;;;;+4/p-4
InChI key
SLIOYUPLNYLSSR-UHFFFAOYSA-J
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애플리케이션
Catalyst for:
- Reduction of carboxamides with hydrosilanes
- Hydrosilylation of siloxanes
- Dehydrocoupling polycondensation reactions
- Hydrolysis of trichlorosilanes
저장 및 안정성
1. Hygroscopic material, always handle in a glove bag or a glove box filled with dry inert gas
2. Recommended for one time use to prevent water absorption and degradation. If necessary, once opened, repack and seal under dry inert gas.
3. Store with care. Prevent from light. Always store in well-sealed containers in a dry inert atmosphere. Recommended to store containers in a secondary desiccator with desiccant in a dry inert atmosphere.
2. Recommended for one time use to prevent water absorption and degradation. If necessary, once opened, repack and seal under dry inert gas.
3. Store with care. Prevent from light. Always store in well-sealed containers in a dry inert atmosphere. Recommended to store containers in a secondary desiccator with desiccant in a dry inert atmosphere.
Packaged under dry Nitrogen gas
기타 정보
Catalyst for the hydrosilylation of olefins
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 1
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
이미 열람한 고객
de Vekki, D. A.; et al.
Russ. J. Gen. Chem., 75, 1757-1757 (2005)
Alan R Bassindale et al.
Chemical communications (Cambridge, England), (12), 1382-1383 (2003-07-05)
Hexasilsesquioxane cages (T6) have been prepared from a range of alkyl and aryl trichlorosilanes using a "non aqueous" hydrolysis with dimethyl sulfoxide.
Toal, S. J.; et al.
Organometallics, 24, 3081-3081 (2005)
Shiori Hanada et al.
Journal of the American Chemical Society, 131(41), 15032-15040 (2009-09-30)
The synergetic effect of two Si-H groups leads to efficient reduction of carboxamides to amines by platinum catalysts under mild conditions. The rate of the reaction is dependent on the distance of two Si-H groups; 1,1,3,3-tetramethyldisiloxane (TMDS) and 1,2-bis(dimethylsilyl)benzene are
J.L. Speier
Adv. Organomet. Chem., 17, 407-407 (1979)
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