901742
Dimethyl[(1-pyrrolidinyl)phenyl]-amine nickel(II) chloride
≥95%
동의어(들):
(PyrNMeNN)Ni-Cl, (SP-4-4)-Chloro[N1,N1-dimethyl-N2-[2-(1-pyrrolidinyl-κN)phenyl]-1,2-benzenediaminato-κN1,κN2]nickel, Second-generation Nickamine
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모든 사진(1)
About This Item
실험식(Hill 표기법):
C18H22ClN3Ni
Molecular Weight:
374.53
UNSPSC 코드:
12352101
추천 제품
분석
≥95%
양식
powder or crystals
반응 적합성
core: nickel
reagent type: catalyst
SMILES string
CN(C)C1=C(C=CC=C1)NC2=CC=CC=C2N3CCCC3.[Ni].Cl
애플리케이션
As reported by Xile Hu′s lab, this nickel(II) pincer complex is an improvement from the first-generation Nickamine as an efficient Ni catalyst for Kumada and Suzuki-Miyaura cross-coupling of both nonactivated primary and secondary alkyl halides.
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point (°F)
Not applicable
Flash Point (°C)
Not applicable
가장 최신 버전 중 하나를 선택하세요:
A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions.
Franco TD, et al.
Helvetica Chimica Acta, 99(11), 830-847 (2016)
From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides.
Garcia PMP, et al.
ACS Catalysis, 6 (1), 258-261 (2016)
문서
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..
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