927783

XPhos Pd G3 ChemBeads

• 동의어(들): (2-Dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, XPhos-G3-Palladacycle, XPhos-Pd-G3
• 실험식(Hill 표기법): C₄₆H₆₂NO₃PPdS
• CAS Number: 1445085-55-1
• Molecular Weight: 846.45
• MDL number: MFCD22666043
• UNSPSC 코드: 12352101
• NACRES: NA.82

속성

• 양식: solid
• Quality Level: 100
• 구성: ~ 4 wt.% loading of catalyst
• 반응 적합성: reagent type: catalyst; reaction type: Cross Couplings
• SMILES string: [Pd](O[S](=O)(=O)C)c5c(cccc5)c6c(cccc6)N.P(C4CCCCC4)(C3CCCCC3)c1c(cccc1)c2c(cc(cc2C(C)C)C(C)C)C(C)C
• InChI key: NKKHABPORDUWIG-UHFFFAOYSA-M

설명

일반 설명

XPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XPhos Pd G3 is an excellent reagent for Suzuki cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

For larger scale uses, product also available in powdered form (763381)

애플리케이션

XPhos Pd G3 may be used in the following reactions:

• Cyanation reaction of heterocyclic halides.
• Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents.
• Coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides.

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기타 정보

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

안전성 정보

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3