919780
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) ChemBeads
Synonym(s):
Pd(dppf)Cl2
About This Item
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form
solid
Quality Level
composition
~ 4 wt.% loading of catalyst
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
InChI
1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q2*-1;;;2*+2/p-2
InChI key
NXQGGXCHGDYOHB-UHFFFAOYSA-L
Related Categories
Application
Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:
- Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
- Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
- Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.
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For larger scale uses, product also available in powdered form (697230) & (931217)
Other Notes
Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation
ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand
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Danger
hcodes
Hazard Classifications
Carc. 1B Inhalation
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Certificates of Analysis (COA)
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Articles
ChemBeads, catalyst-coated glass beads, dispense solid chemical reagents for nanomole-scale high-throughput reaction screening.
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