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Merck
모든 사진(1)

문서

931578

Sigma-Aldrich

Ruthenium(III) chloride hydrate

≥99.9% trace metals basis

동의어(들):

Ruthenium trichloride, Trichlororuthenium hydrate

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About This Item

Linear Formula:
RuCl3 · xH2O
CAS Number:
Molecular Weight:
207.43 (anhydrous basis)
MDL number:
UNSPSC 코드:
12352302
NACRES:
NA.21

Quality Level

분석

≥99.9% trace metals basis

형태

powder

불순물

≤1000.0 ppm (trace metals analysis)

solubility

acetone: soluble ((lit.))
ethanol: soluble
water: soluble

density

3.11 g/cm3

SMILES string

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI key

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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일반 설명

Ruthenium chloride hydrate is a dark brown or black solid often used as a powder. The hydrate is hygroscopic and is soluble in water, ethanol, acetone, and a wide range of polar organic solvents. The anhydrous form is insoluble.
Industrially, ruthenium trichloride hydrate is produced by dissolving ruthenium oxides in hydrochloric acid. The hydrated salt is obtained by recrystallization.

애플리케이션

Ruthenium chloride is most used as a precursor for the synthesis of ruthenium complexes. Our RuCl3·H2O with 99.9% trace metals purity is well-suited for applications in materials science. One common application of ruthenium trichloride hydrate is in the synthesis of ruthenium nanoparticles, which are used as catalysts or composited with other materials and used as co-catalysts for both oxygen and hydrogen evolution reactions. Researchers have used our ruthenium chloride hydrate to produce high-quality, catalytically active ruthenium nanoparticles and ruthenium oxide nanoparticles.
Another common application of ruthenium chloride hydrate is as a precursor for single-atom catalysts. For example, scientists have used ruthenium chloride hydrate for the synthesis of ruthenium single-atom-doped ZrO2 particles to catalyze nitrogen fixation and for the synthesis of ruthenium single-atom-doped MXenes to catalyze hydrogen evolution. A third common application of ruthenium chloride hydrate is in the synthesis of metal alloys, like PtRuIr, or PtRuFe, which are investigated for electrocatalysis, usually the oxidation of simple organics like methanol or formic acid.
For use in all these applications, also consider our higher-purity ruthenium chloride hydrate, 463779, with trace metals purity greater than 99.98%, which offers the best reproducibility and purity.

픽토그램

CorrosionExclamation markEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서 라이브러리 방문

Synthesis and Activities of Rutile IrO2 and RuO2 Nanoparticles for Oxygen Evolution in Acid and Alkaline Solutions
Lee, Y., Suntivich, J., et al.
The Journal of Physical Chemistry Letters, 3, 399?404-399?404 (2012)
Heteroatom-Mediated Interactions between Ruthenium Single Atoms and an MXene Support for Efficient Hydrogen Evolution
Ramalingam, V., et al.
Advanced Materials, 31, e1903841-e1903841 (2019)
High Performance PtRuIr Catalysts Supported on Carbon Nanotubes for the Anodic Oxidation of Methanol
Liao, S., Holmes, K.A., et al.
Journal of the American Chemical Society, 128, 3504-3505 (2006)
Nitrogen Fixation by Ru Single-Atom Electrocatalytic Reduction
Tao, H., Choi, C., et al.
Chem, 5, 204-214 (2019)
Vinoth Ramalingam et al.
Advanced materials (Deerfield Beach, Fla.), 31(48), e1903841-e1903841 (2019-10-18)
A titanium carbide (Ti3 C2 Tx ) MXene is employed as an efficient solid support to host a nitrogen (N) and sulfur (S) coordinated ruthenium single atom (RuSA ) catalyst, which displays superior activity toward the hydrogen evolution reaction (HER).

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