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Merck
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문서

8.03945

Sigma-Aldrich

Iron(III) chloride

greener alternative

anhydrous for synthesis

동의어(들):

Iron(III) chloride, Ferric chloride, Iron trichloride

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About This Item

실험식(Hill 표기법):
Cl3Fe
CAS Number:
Molecular Weight:
162.20
MDL number:
UNSPSC 코드:
12352302
EC 인덱스 번호:
231-729-4
NACRES:
NA.22

vapor pressure

1 hPa ( 20 °C)

Quality Level

형태

powder

효능

316 mg/kg LD50, oral (Rat)

환경친화적 대안 제품 특성

Catalysis
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pH

1 (20 °C, 200 g/L in H2O)

mp

306 °C (decomposition)

solubility

920 g/L (Hydrolysis)

density

2.89 g/cm3 at 25 °C

벌크 밀도

1000 kg/m3

환경친화적 대안 카테고리

저장 온도

2-30°C

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

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일반 설명

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애플리케이션

Iron(III) chloride (FeCl3) can be used as a catalyst:
  • For the oxidation of glucose to gluconic acid in water.
  • To synthesize 2-iodo substituted benzo[b]thiophenes by iodocyclization of 2-alkynylthioanisoles in the presence of sodium iodide and ethanol as a solvent.
  • In the glycosylation sugars in the presence of allyl and alkynyl alcohols to synthesize corresponding glycosides.
  • To prepare 1,2-trans glycosyl azides by azido glycosylation of glycosyl β-peracetates.

분석 메모

Assay (iodometric): ≥ 98.0 %
Identity (Fe): passes test
Identity (Cl): passes test

픽토그램

CorrosionExclamation mark

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서 라이브러리 방문

이미 열람한 고객

Oxidative conversion of glucose to gluconic acid by iron (III) chloride in water under mild conditions
Zhang H, et al.
Green Chemistry, 18(8), 2308-2312 (2016)
Green synthesis of benzo [b] thiophenes via iron (III) mediated 5-endo-dig iodocyclization of 2-alkynylthioanisoles
Kesharwani T, et al.
Tetrahedron Letters, 57(3), 411-414 (2016)
Iron (III) chloride catalyzed glycosylation of peracylated sugars with allyl/alkynyl alcohols
Narayanaperumal S, et al.
Journal of the Brazilian Chemical Society, 23, 1982-1988 (2012)
Santosh B Salunke et al.
Chemical communications (Cambridge, England), 47(37), 10440-10442 (2011-08-16)
A highly efficient and mild method for azido glycosylation of glycosyl β-peracetates to 1,2-trans glycosyl azides was developed by using inexpensive FeCl(3) as the catalyst. In addition, we demonstrated, for the first time, that FeCl(3) in combination with copper powder

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