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Merck
모든 사진(1)

주요 문서

73594

Supelco

Ammonium acetate

LiChropur, eluent additive for LC-MS

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About This Item

Linear Formula:
CH3CO2NH4
CAS Number:
Molecular Weight:
77.08
Beilstein:
4186741
EC Number:
MDL number:
UNSPSC 코드:
12000000
eCl@ss:
39021908
PubChem Substance ID:
NACRES:
NB.21

Grade

eluent additive for LC-MS

Quality Level

Agency

suitable for ASTM® 7968
suitable for ASTM® 7979
suitable for DIN 38407-42
suitable for EPA 1633
suitable for EPA 533
suitable for EPA 537.1
suitable for EPA 8327
suitable for EPA ACB B21-02
suitable for EPA ACB B23-05b
suitable for GB 31604.35-2016
suitable for GB 5009.253-2016
suitable for ISO 21675 2019
suitable for ISO 25101
suitable for ISO/CEN 15968-2010

규정 준수

suitable for FDA C-010.02

분석

≥99.0% (calc. on dry substance, T)

형태

solid

품질

LiChropur

기술

LC/MS: suitable

불순물

insoluble matter, passes filter test
≤1% water

무기 잔류물

≤0.01% (as SO4)

pH

6.2-7.5 (25 °C, 1 M in H2O)

mp

110-112 °C (dec.) (lit.)

solubility

H2O: 1 M at 20 °C, clear, colorless

음이온 미량물

chloride (Cl-): ≤5 mg/kg
nitrate (NO3-): ≤10 mg/kg
sulfate (SO42-): ≤10 mg/kg

양이온 미량물

Al: ≤1 mg/kg
As: ≤0.1 mg/kg
Ba: ≤1 mg/kg
Bi: ≤1 mg/kg
Ca: ≤5 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
K: ≤5 mg/kg
Li: ≤1 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Mo: ≤1 mg/kg
Na: ≤5 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Sr: ≤1 mg/kg
Zn: ≤1 mg/kg

SMILES string

N.CC(O)=O

λ

1 M in H2O

UV 흡수

λ: 260 nm Amax: ≤0.015
λ: 280 nm Amax: ≤0.010

적합성

passes test for LC-MS

InChI

1S/C2H4O2.H3N/c1-2(3)4;/h1H3,(H,3,4);1H3

InChI key

USFZMSVCRYTOJT-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

Ammonium acetate exists as a white crystal. It is prepared from acetic acid and ammonia by neutralization to pH 7.0. It is widely used in analytical chemistry, drugs and in textile dyeing.

애플리케이션

Ammonium acetate has been used to prepare eluents for UPLC-MS/MS and HPLC-MS/MS to compare the matrix effect of 9 pharmaceutical compounds in aqueous environmental samples. It has also been used as an additive to improve detection of phosphopeptides using MALDI-MS.

추천 제품

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

법적 정보

ASTM is a registered trademark of American Society for Testing and Materials
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

애플리케이션

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

개인 보호 장비

Eyeshields, Gloves, type N95 (US)


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시험 성적서(COA)

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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Dale L. Perry
Handbook of Inorganic Compounds, 17-17 (1995)
Jet C Van De Steene et al.
Journal of the American Society for Mass Spectrometry, 19(5), 713-718 (2008-03-18)
When developing an LC-MS/MS-method matrix effects are a major issue. The effect of co-eluting compounds arising from the matrix can result in signal enhancement or suppression. During method development much attention should be paid to diminishing matrix effects as much
Enhanced detection of phosphopeptides in matrix-assisted laser desorption/ionization mass spectrometry using ammonium salts.
Asara JM, Allison J.
Journal of the American Society For Mass Spectrometry, 10(1), 35-44 (1999)
Comparison of matrix effects in HPLC-MS/MS and UPLC-MS/MS analysis of nine basic pharmaceuticals in surface waters.
Van De Steene JC, Lambert WE.
Journal of the American Society For Mass Spectrometry, 19(5), 713-718 (2008)
J M Asara et al.
Journal of the American Society for Mass Spectrometry, 10(1), 35-44 (1999-01-15)
Matrix-assisted laser desorption/ionization mass spectrometry (MALDI MS) has been used successfully to detect phosphorylation sites in proteins. Applications may be limited by the low response of phosphopeptides compared to nonphosphorylated peptides in MALDI MS. The addition of ammonium salts to

문서

This study demonstrates the impact of various mobile phase modifiers on the separation; formate modifiers outperform acetate in terms of MS signals (or sensitivity) and chromatographic resolution.

LC-MS method separates 32 PFAS compounds in drinking water following EPA methods 533, 537, and 537.1. EPA 8327.

Learn about the separation of several charge variants of two monoclonal antibodies, NISTmAb and Infliximab, using a polymeric cation exchange column and MS-compatible mobile phases.

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모두 보기

Chromatograms

application for HPLCapplication for UHPLC

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