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Merck
모든 사진(4)

주요 문서

208043

Sigma-Aldrich

Sodium sulfide nonahydrate

ACS reagent, ≥98.0%

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About This Item

Linear Formula:
Na2S·9H2O
CAS Number:
Molecular Weight:
240.18
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.21
분석:
≥98.0%
Grade:
ACS reagent
양식:
crystals or chunks

Grade

ACS reagent

Quality Level

분석

≥98.0%

양식

crystals or chunks

반응 적합성

reagent type: catalyst
core: sodium

색상

colorless to slightly yellow

음이온 미량물

SO32- and S2O32-: ≤0.1%

양이온 미량물

Fe:, passes test
NH4+: ≤0.005%

저장 온도

2-8°C

SMILES string

O.O.O.O.O.O.O.O.O.[Na]S[Na]

InChI

1S/2Na.9H2O.S/h;;9*1H2;

InChI key

UIINQVYGFKNSPA-UHFFFAOYSA-N

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일반 설명

Sodium sulfide nonahydrate participates in the conversion of nitroxides to amines, via reduction.

애플리케이션

Sodium sulfide nonahydrate has been used as a source of H2S, to study the effect of H2S on amyloid fibrils associated with neurodegenerative diseases. It has been used in the preparation of sulfide standards for the quantitative analysis of sulfides in raw wastewater (sewage) samples.
It serves as a catalyst during synthesis of thioamides.
Sodium sulfide nonahydrate has been used as a standard for the quantification of volatile sulfur compounds in cheese samples by gas chromatography. It reacts with 4-(2′-hydroxyaryl)-2-(N,N-dialkylamino)-1,3-dithiolium perchlorates in ethanol at room temperature and boiling ethanol to form 1,3-dithiole-2-thiones and 2′-hydroxyacetophenones, respectively. Sodium sulfide nonahydrate may be used as a reducing agent for the conversion of vic-dibromides to the corresponding olefins via reductive debromination.

픽토그램

Skull and crossbonesCorrosionEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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문서 라이브러리 방문

이미 열람한 고객

Reduction of nitroxides to amines by sodium sulfide.
Kornblum N and Pinnick HW.
The Journal of Organic Chemistry, 37(12), 2050-2051 (1972)
Preservation and simultaneous analysis of relevant soluble sulfur species in sewage samples
Keller-Lehmann B, et al.
Proceedings of the 2nd International Conference on Intelligent Technologies and Engineering Systems (ICITES2013). Springer International Publishing, 2014., 26 (2006)
A new reduction system: combination of sodium sulfide (sodium hydrosulfide) with phase transfer agent in a two-phase mixture. Reductive debromination ofvic-dibromides to olefins.
Nakayama J, et al.
Tetrahedron Letters, 24(29), 3001-3004 (1983)
Reaction of 4-(2'-Hydroxyaryl)-1, 3-dithiolium Salts with Sodium Sulfide. A Selective Synthesis of 2'-Hydroxyacetophenones.
Birsa ML.
Synthetic Communications, 33(17), 3071-3076 (2003)
Veinot, J.G.C. et al.
Chemistry of Materials, 9, 2117-2117 (1997)

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