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Merck
모든 사진(1)

주요 문서

CRM68173

Supelco

Atrazine-desethyl

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

동의어(들):

2-Amino-4-chloro-6-isopropylamino-1,3,5-triazine, Desethylatrazine

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About This Item

실험식(Hill 표기법):
C6H10ClN5
CAS Number:
Molecular Weight:
187.63
Beilstein:
610488
MDL number:
UNSPSC 코드:
41116107
NACRES:
NA.24

Grade

certified reference material

Quality Level

제품 라인

TraceCERT®

grade

TraceCERT®

유통기한

limited shelf life, expiry date on the label

제조업체/상표

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

SMILES string

CC(C)Nc1nc(N)nc(Cl)n1

InChI

1S/C6H10ClN5/c1-3(2)9-6-11-4(7)10-5(8)12-6/h3H,1-2H3,(H3,8,9,10,11,12)

InChI key

DFWFIQKMSFGDCQ-UHFFFAOYSA-N

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일반 설명

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Atrazine-desethyl is a major cytochrome P450s (CYPs) derived metabolite of the herbicide atrazine, widely used for protection against broadleaf and grassy weeds in various crops. It has more stability than its parent atrazine and the same endocrine-disrupting toxicity.
The parent compound atrazine is not approved for use in the European Union (EU) as per the legislation 2004/248/EC of 24th March 2004. But atrazine has a maximum residue limit (MRL) set in the range of 0.01-2 mg/kg for its presence in soybean, corn, and wheat crops by the United States (US) and the European Union (EU).

애플리케이션

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The atrazine-desethyl CRM may also find below-given uses:

  • Analysis of atrazine and its major metabolites in water and soil samples by using multi-walled carbon nanotubes for solid-phase extraction (SPE) and gas chromatography-mass spectrometry (GC-MS) for detection
  • QuEChERS-based extraction and liquid chromatography-diode-array detection (LC-DAD) of atrazine and its principal metabolites in natural water samples
  • Development of a carboxyl-modified polyacrylonitrile nanofibers mat (COOH-PAN NFsM) for the solid phase extraction (SPE) of atrazine and its metabolites from environmental water samples followed by their determination using high-performance liquid chromatography-diode array detector (HPLC-DAD)
  • Analysis of simazine and atrazine extracted from river water by reversed-phase liquid chromatography with ultraviolet detection (LC-UV)
  • Simultaneous separation and determination of atrazine and its main metabolites in 15 samples each of soybean, corn, and wheat by a novel UPLC-ESI-MS/MS-based method

법적 정보

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

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픽토그램

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신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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시험 성적서(COA)

Lot/Batch Number

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문서 라이브러리 방문

Determination of simazine and atrazine in river water by cloud-point extraction and high-performance liquid chromatography
de Pra Urio R and Masini J C
Analytical Letters, 50(7) (2017)
Guang Min et al.
The Science of the total environment, 396(1), 79-85 (2008-03-29)
A novel, simple, cost-effective, and sensitive method was developed for the determination of atrazine and its principal metabolites namely deisopropyl-atrazine (DIA) and deethyl-atrazine (DEA) in water and soil samples using multi-walled carbon nanotubes as solid-phase extraction (SPE) adsorbents coupled with
Toxicity, degradation and analysis of the herbicide atrazine
Singh S, et al.
Environmental Chemistry Letters, 16(1) (2018)
Weixin Cao et al.
Journal of chromatography. A, 1491, 16-26 (2017-02-27)
Carboxyl modified polyacrylonitrile nanofibers mat (COOH-PAN NFsM) was prepared as a novel solid-phase extraction (SPE) adsorbent for the rapid and effective extraction of atrazine (ATZ) and its toxic metabolites deisopropylatrazine (DIA) and deethylatrazine (DEA) from environmental water samples. Without any
Analysis of herbicide atrazine and its degradation products in cereals by ultra-performance liquid chromatography-mass spectrometry
Liang S, et al.
Analytical Methods : Advancing Methods and Applications, 8(17) (2016)

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