- Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent.
Copper-catalyzed trifluoromethylation of aryl boronic acids using a CF3+ reagent.
Chemical communications (Cambridge, England) (2011-03-08)
Jun Xu, Dong-Fen Luo, Bin Xiao, Zhao-Jing Liu, Tian-Jun Gong, Yao Fu, Lei Liu
PMID21380454
초록
A copper-catalyzed process for trifluoromethylation of aryl, heteroaryl, and vinyl boronic acids has been developed. The reaction is conducted under mild conditions and shows tolerance to moisture and a variety of functional groups.
MATERIALS