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112186

Sigma-Aldrich

4-Bromobenzyl bromide

98%

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Synonym(s):
α,4-Dibromotoluene
Linear Formula:
BrC6H4CH2Br
CAS Number:
Molecular Weight:
249.93
Beilstein:
606498
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

solid

mp

62-64 °C (lit.)

SMILES string

BrCc1ccc(Br)cc1

InChI

1S/C7H6Br2/c8-5-6-1-3-7(9)4-2-6/h1-4H,5H2

InChI key

YLRBJYMANQKEAW-UHFFFAOYSA-N

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This Item
403229B17905154253
4-Bromobenzyl bromide 98%

Sigma-Aldrich

112186

4-Bromobenzyl bromide

Benzyl bromide reagent grade, 98%

Sigma-Aldrich

B17905

Benzyl bromide

form

solid

form

-

form

liquid

form

-

mp

62-64 °C (lit.)

mp

26-30 °C (lit.)

mp

−3-−1 °C (lit.)

mp

57-59 °C (lit.)

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

100

Application

4-Bromobenzyl bromide was used to prepare a 20-member aminomethyl-substituted biaryl library via sequential N-alkylation of various amines.

Pictograms

CorrosionHealth hazard

Signal Word

Danger

Hazard Statements

Hazard Classifications

Resp. Sens. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Slide 1 of 4

1 of 4

M G Organ et al.
Journal of combinatorial chemistry, 3(5), 473-476 (2001-09-11)
Described herein is the semiautomated preparation of a 20-member aminomethyl-substituted biaryl library. The two-step solution-phase synthesis was achieved via sequential N-alkylation of various amines with either 3- or 4-bromobenzyl bromide and Suzuki cross-coupling of the resultant aryl bromides with various
E V Sargent et al.
Drug and chemical toxicology, 22(4), 583-593 (1999-10-28)
As part of an occupational hazard evaluation, p-bromobenzyl bromide (p-BBB) was evaluated for genotoxic activity in the Ames microbial mutagenicity assay, the alkaline elution assay for DNA strand breaks in rat hepatocytes and the in vitro chromosome aberration assay in

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