115150

Thiophosgene

• Synonym(s): Thiocarbonyl chloride
• Linear Formula: CSCl₂
• CAS Number: 463-71-8
• Molecular Weight: 114.98
• NACRES: NA.22
• PubChem Substance ID: 24847201
• eCl@ss: 38020402
• UNSPSC Code: 12352000
• EC Number: 207-341-6
• MDL number: MFCD00004918
• Beilstein/REAXYS Number: 1633495

Properties

• vapor density: 4 (vs air)
• Quality Segment: 200
• reaction suitability: reaction type: Carbonylations
• refractive index: n20/D 1.548 (lit.)
• bp: 70-75 °C (lit.)
• density: 1.50 g/mL at 20 °C (lit.)
• functional group: chloro
• storage temp.: 2-8°C
• SMILES string: ClC(Cl)=S
• InChI: 1S/CCl2S/c2-1(3)4
• InChI key: ZWZVWGITAAIFPS-UHFFFAOYSA-N

Description

Application

Reagent used to prepare a bulky thiourea ligand for palladium-catalyzed aerobic oxidation of alcohols to aldehydes and ketones.

Safety Information

• pictograms: GHS06,GHS05
• signalword: Danger
• hcodes: H302,H315,H318,H331,H335
• pcodes: P261 - P280 - P301 + P312 - P302 + P352 - P304 + P340 + P311 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• wgk: WGK 1
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter