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115150

Sigma-Aldrich

Thiophosgene

Synonym(s):

Thiocarbonyl chloride

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About This Item

Linear Formula:
CSCl2
CAS Number:
463-71-8
Molecular Weight:
114.98
Beilstein/REAXYS Number:
1633495
EC Number:
207-341-6
MDL number:
MFCD00004918
UNSPSC Code:
12352000
eCl@ss:
38020402
PubChem Substance ID:
24847201
NACRES:
NA.22

vapor density

4 (vs air)

Quality Level

200

reaction suitability

reaction type: Carbonylations

refractive index

n20/D 1.548 (lit.)

bp

70-75 °C (lit.)

density

1.50 g/mL at 20 °C (lit.)

functional group

chloro

storage temp.

2-8°C

SMILES string

ClC(Cl)=S

InChI

1S/CCl2S/c2-1(3)4

InChI key

ZWZVWGITAAIFPS-UHFFFAOYSA-N

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Application

Reagent used to prepare a bulky thiourea ligand for palladium-catalyzed aerobic oxidation of alcohols to aldehydes and ketones.

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 1

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
STBJ7925
STBH8658
STBH9037
STBH9036
STBH8659

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Christof Jung et al.
The journal of physical chemistry. A, 110(16), 5317-5325 (2006-04-21)
The dispersed fluorescence spectrum of the ground electronic state of thiophosgene, SCCl2, is analyzed in a very complex region of vibrational excitation, 7000-9000 cm(-1). The final result is that most of the inferred excited vibrational levels are assigned in terms
Cheng Li et al.
Colloids and surfaces. B, Biointerfaces, 171, 159-166 (2018-07-22)
Dual mode imaging technology is widely developed to achieve the early-stage precision cancer diagnosis. Here we designed a dual-modal magnetic resonance/near infrared fluorescence optical imaging contrast agent (GdF-SS-NIR783) with the fluorescence activatable and safer gadofullerene. The nanoprobes were fabricated by
W Kedzierski et al.
The Journal of chemical physics, 120(19), 9087-9089 (2004-07-23)
A special xenon matrix detector has been used to study the production of S(1S) following controlled electron impact on thiophosgene (Cl2CS) targets over an electron energy range from threshold to 400 eV. Time-of-flight spectroscopy has been used to measure S(1S)
T A Lewis et al.
Journal of bacteriology, 177(8), 2204-2208 (1995-04-01)
Pseudomonas sp. strain KC transforms carbon tetrachloride into carbon dioxide and nonvolatile products, without chloroform as an intermediate. To define the pathway for hydrolysis, nonvolatile products were analyzed. Condensation products containing the carbon atom of carbon tetrachloride as carbonyl and
Youlia Hagooly et al.
The Journal of organic chemistry, 73(17), 6780-6783 (2008-08-13)
A general preparation for aromatic and aliphatic, cyclic as well as linear, symmetric and asymmetric difluoromethylenedioxy derivatives is described. The alcohols were reacted with thiophosgene to give thiocarbonates, which in turn were reacted with BrF3. The fluorination step is complete
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