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115835

Sigma-Aldrich

2-Bromoacetophenone

98%

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Synonym(s):
ω-Bromoacetophenone, Phenacyl bromide
Linear Formula:
C6H5COCH2Br
CAS Number:
Molecular Weight:
199.04
Beilstein/REAXYS Number:
606474
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

98%

form

solid

bp

135 °C/18 mmHg (lit.)

mp

48-51 °C (lit.)

SMILES string

BrCC(=O)c1ccccc1

InChI

1S/C8H7BrO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2

InChI key

LIGACIXOYTUXAW-UHFFFAOYSA-N

Gene Information

human ... PTPN6(5777)

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1 of 4

This Item
115665389390669466
2-Bromoacetophenone 98%

115835

2-Bromoacetophenone

2-Bromo-4′-methoxyacetophenone 97%

115665

2-Bromo-4′-methoxyacetophenone

2-Bromo-4′-fluoroacetophenone 97%

389390

2-Bromo-4′-fluoroacetophenone

bp

135 °C/18 mmHg (lit.)

bp

-

bp

150 °C/12 mmHg (lit.)

bp

-

form

solid

form

solid

form

solid

form

solid

mp

48-51 °C (lit.)

mp

69-71 °C (lit.)

mp

47-49 °C (lit.)

mp

46-56 °C

Gene Information

human ... PTPN6(5777)

Gene Information

human ... PTPN6(5777)

Gene Information

human ... PTPN6(5777)

Gene Information

human ... PTPN6(5777)

Application

2-Bromoacetophenone has been used in the analysis of organic acids involving the formation of phenacyl derivatives.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

Storage Class

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Herein is reported a simple and efficient one-pot three-component synthesis of pyrrolo[1,2-c]pyrimidine derivatives starting from various substituted pyrimidines, 2-bromoacetophenones, and electron deficient alkynes in epoxides acting both as reaction medium and HBr scavanger. This method proved to be very lucrative

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