Skip to Content
MilliporeSigma
All Photos(4)

Documents

124915

Sigma-Aldrich

4-Formylbenzoic acid

97%

Sign Into View Organizational & Contract Pricing

Synonym(s):
4-Carboxybenzaldehyde, Benzaldehyde-4-carboxylic acid, Terephthalaldehydic acid
Linear Formula:
HO2CC6H4CHO
CAS Number:
Molecular Weight:
150.13
Beilstein/REAXYS Number:
471734
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

form

powder

mp

247 °C (lit.)

SMILES string

[H]C(=O)c1ccc(cc1)C(O)=O

InChI

1S/C8H6O3/c9-5-6-1-3-7(4-2-6)8(10)11/h1-5H,(H,10,11)

InChI key

GOUHYARYYWKXHS-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

4-Formylbenzoic acid is an important intermediate in the synthesis of terepthalic acid. It reacts with barium carbonate to yield two-dimensional barium(II) coordination polymer.

Application

4-Formylbenzoic acid has been used as reagent during esterification of 2,2,6,6-tetramethyl-4-oxopiperidinyl-1-oxyl to yield 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl 4-formylbenzoate.
It can also be used as a reagent to synthesize acid functionalized mesoporous silica catalyst by the condensation of its aldehyde group with -NH2 of amine functionalized silica.

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Highly ordered acid functionalized SBA-15: a novel organocatalyst for the preparation of xanthenes.
Nandi M, et al.
Chemical Communications (Cambridge, England), 47(23), 6677-6679 (2011)
Elena Sartori et al.
Journal of the American Chemical Society, 129(25), 7785-7792 (2007-06-05)
Interactions between reactive free radicals (r) with stable mononitroxyl radicals (N) and bisnitroxyl radicals (N-X-N) were studied by time-resolved electron paramagnetic resonance (TR-EPR). Reactive spin-polarized free radicals (r#), with non-Boltzmann population of spin states were produced by laser flash photolysis
Topochemical studies. VIII. The crystal and molecular sturtures of two polymorphs of 4-formylbenzoic acid.
Haisa MASAO, et al.
Acta Crystallographica Section B, Structural Crystallography and Crystal Chemistry, 32(3), 857-860 (1976)
The first two-dimensional barium coordination polymer based on neutral and deprotonated 4-formylbenzoic acid.
Deng ZP, et al.
Applied Organometallic Chemistry, 21(11), 978-982 (2007)
Yves Meyer et al.
Organic & biomolecular chemistry, 8(8), 1777-1780 (2010-05-08)
This study focuses on the disassembly-behavior of self-immolative pro-fluorescent linkers under physiological conditions and through an enzyme-initiated domino reaction. The targeted linkers are based on para-aminobenzylalcohol (PABA) or hemithioaminal derivatives of para-carboxybenzaldehyde or glyoxilic acid. We found that a fine

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service