128007

1,5-Dibromopentane

97%

• Synonym(s): Pentamethylene dibromide
• Linear Formula: Br(CH₂)₅Br
• CAS Number: 111-24-0
• Molecular Weight: 229.94
• Beilstein/REAXYS Number: 1209245
• EC Number: 203-849-7
• MDL number: MFCD00000268
• UNSPSC Code: 12352100
• PubChem Substance ID: 24847812
• NACRES: NA.22

Properties

• vapor density: 8 (vs air)
• Quality Level: 100
• assay: 97%
• form: liquid
• refractive index: n20/D 1.512 (lit.)
• bp: 110 °C/15 mmHg (lit.)
• mp: −34 °C (lit.)
• density: 1.688 g/mL at 25 °C (lit.)
• SMILES string: BrCCCCCBr
• InChI: 1S/C5H10Br2/c6-4-2-1-3-5-7/h1-5H2
• InChI key: IBODDUNKEPPBKW-UHFFFAOYSA-N

Description

General description

1,5-Dibromopentane is a growth supplement for Yarrowia lipolytica 3589, a tropical marine yeast.

Application

1,5-Dibromopentane can be used to prepare:

• Derivatives of 5-pyrazolones.
• O-alkylated phloroglucinol derivatives, which forms the core of poly(alkyl aryl ether) dendrimers.
• Intermediate for dezocine viz, (R)-(+)-1-(5-bromopentyl)-1-methyl-7-methoxy-2-tetralone using 1-methyl-7-methoxy-2-tetralone.

1,5-Dibromopentane was used in the preparartion of 1,5-di-Grignard reagent. It was also used in the synthesis of novel spirocyclic pyrrolidones.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319
• pcodes: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 174.2 °F - closed cup
• flash_point_c: 79 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter