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form
solid
Quality Level
reaction suitability
reagent type: oxidant
mp
232 °C (dec.) (lit.)
SMILES string
CN(C)C.O=S(=O)=O
InChI
1S/C3H9N.O3S/c2*1-4(2)3/h1-3H3;
InChI key
DXASQZJWWGZNSF-UHFFFAOYSA-N
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Application
Reactant for sulfation reactions involving:
Nucleophile for the synthesis of α-tosyloxy ketones
- Synthesis of sulfate-conjugated resveratrol metabolites
- Chitooligosaccharides used for anti-HIV-1 activity
- Dodecyl thioglycopyranoside used as a surfactant for enantiomeric separation
- Glycosaminoglycans which facilitate activation of signaling pathways dependent on sulfation pattern
- Polysaccharides as heparan sulfate mimetics
Nucleophile for the synthesis of α-tosyloxy ketones
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PloS one, 8(7), e68031-e68031 (2013-07-12)
24S- and 27-hydroxycholesterol (24OHC and 27OHC) are potent regulators of different biochemical systems in vitro and are the major circulating oxysterols. A small fraction of these oxysterols has been reported to be sulphated but there are no detailed studies. We
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 34(4), 482-488 (2017-01-21)
After administration of steroids to animals the steroids are partially metabolised in the liver and kidney to phase 2 metabolites, i.e., glucuronic acid or sulphate conjugates. During analysis these conjugated metabolites are normally deconjugated enzymatically with aryl sulphatase and glucuronidase
Carbohydrate polymers, 236, 116052-116052 (2020-03-17)
In this study, a series water soluble sulfate polysaccharides (SPS) with different degrees of substitutions (DS = 0.02∼0.28) were prepared using a linear water-insoluble β-d-(1→3)-glucan. SPS-1, SPS-3 and SPS-7 with substitution degrees of 0.02, 0.06 and 0.25 were used as templates to
Macromolecular bioscience, 20(2), e1900403-e1900403 (2019-12-31)
Sulfated cellulose (CS) represents an interesting biopolymer due to bioactivity comparable to heparin. However, use of CS for making surface coatings or hydrogels requires the presence of reactive groups for covalent reactions. Here, an approach is presented to oxidize cellulose
Biopolymers, 103(10), 539-549 (2015-04-11)
The 6-amino-6-deoxychitosan (NC) and their 2, 6-di-N-sulfonated derivatives were prepared via N-phthaloylation, tosylation, azidation, hydrazinolysis, reduction of azide groups and N-sulfonation, and their structures were systematically characterized by FT-IR, 2D HSQC NMR, XRD, gel permeation chromatography (GPC), and elemental analysis.
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