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Key Documents

206105

Sigma-Aldrich

Ammonium tetrachloroplatinate(II)

99%

Synonym(s):

Platinum(II)-ammonium chloride

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About This Item

Linear Formula:
(NH4)2PtCl4
CAS Number:
Molecular Weight:
372.97
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99%

form

solid

mp

140 °C (dec.) (lit.)

density

2.936 g/mL at 25 °C (lit.)

SMILES string

[H][N+]([H])([H])[H].[H][N+]([H])([H])[H].Cl[Pt--](Cl)(Cl)Cl

InChI

1S/4ClH.2H3N.Pt/h4*1H;2*1H3;/q;;;;;;+2/p-2

InChI key

QJIMNDWDOXTTBR-UHFFFAOYSA-L

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Application

  • Deactivation study of the hydrodeoxygenation of p-methylguaiacol: Studies catalysts prepared using ammonium tetrachloroplatinate(II), focusing on sustainable chemical processes relevant across academic research (Bouxin et al., 2017).

Features and Benefits

Reacts with creatinine (cat. no. 859702) to form various complexes such as [Pt4(creat)2Cl14]7- and [Pt4(creat)6]2- with applications in semiconductors, catalysis, mixed oxidation state studies, and electron conductivity.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Season S Chen et al.
Journal of hazardous materials, 397, 122431-122431 (2020-05-22)
The structural and chemical stability of UiO-66-NH2 and its simulated solar irradiation responsive characteristic make it a suitable metal-organic framework (MOF) candidate as photocatalytic material. Platinum nanoparticles (Pt NPs) are typically immobilized in MOF to enhance the photocatalytic efficiency. However
E Thanasias et al.
Advances in experimental medicine and biology, 755, 47-53 (2012-07-25)
Allergic immediate-type reactions by halogenated compounds of platinum (Pt) (platinum salts) have been described in workers in precious metal refineries and catalyst productions. In both industries there are exposures to many different Pt compounds. It is believed that the most
M Becker et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 133(1), 115-122 (1998-07-09)
The anticancer drug carboplatin has been monitored in rats during treatment by means of in vivo 195Pt NMR spectroscopy at 2.0 T. The purpose of the study was to assess local disposition kinetics in intact tissue following subcutaneous injection of
Francisco Tarazona-Vasquez et al.
The journal of physical chemistry. A, 111(5), 945-953 (2007-02-03)
Density functional theory is used to investigate the complexation ability of dendrimer outer pockets--in both tertiary amine protonated and unprotonated scenarios--toward molecular guests, particularly tetrachloroplatinate(II) and its mono- and diaquated derivatives as well as competing counterions. The effect of the
H C Schuppe et al.
International archives of allergy and immunology, 112(2), 125-132 (1997-02-01)
The sensitizing properties of different complex salts of platinum were defined in vivo by means of the popliteal lymph node (PLN) assay in mice. Hexa- and tetrachloroplatinates were confirmed to be highly immunogenic, inducing vigorous primary immune responses in the

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