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213535

Sigma-Aldrich

2,4-Dichloro-6-methoxy-1,3,5-triazine

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About This Item

Empirical Formula (Hill Notation):
C4H3Cl2N3O
CAS Number:
Molecular Weight:
179.99
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

bp

132-134 °C/49 mmHg (lit.)

mp

86-88 °C (lit.)

functional group

chloro

SMILES string

COc1nc(Cl)nc(Cl)n1

InChI

1S/C4H3Cl2N3O/c1-10-4-8-2(5)7-3(6)9-4/h1H3

InChI key

JKAPWXKZLYJQJJ-UHFFFAOYSA-N

Application

2,4-Dichloro-6-methoxy-1,3,5-triazine was used as reagent in radioimmunoassay for D-Ala2-Dermorphin, a natural peptide extracted from amphibian skin[1]. It was also used in the preparation of:




  • α-cyclodextrin [2]-rotaxanes[2]
  • substituted s-triazines[3]
  • series of chiral derivatizing reagents[4]

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Ryan E Dawson et al.
Organic & biomolecular chemistry, 6(10), 1814-1821 (2008-05-03)
Ten alpha-cyclodextrin [2]-rotaxanes have been prepared with alkane-, stilbene- and azobenzene-based axles, capped through nucleophilic substitution of either 2-chloro-4,6-dimethoxy-1,3,5-triazine or 2,4-dichloro-6-methoxy-1,3,5-triazine in aqueous solution, followed by further substitution of the remaining triazinyl chlorine in some cases when the latter capping
L Negri et al.
Peptides, 2 Suppl 2, 45-49 (1981-01-01)
A selective RIA for D-Ala2-Dermorphin (Der), a natural peptide extracted from amphibian skin, has been developed using an antibody raised in rabbits against Der which has been coupled to BSA through its phenolic hydroxyl groups of tyrosine residues with 2,4-Dichloro-6-methoxy-1,3,5-triazine.
Recent applications of 2, 4, 6-trichloro-1, 3, 5-triazine and its derivatives in organic synthesis.
Blotny G.
Tetrahedron, 62(41), 9507-9522 (2006)
H Brückner et al.
Journal of chromatography. A, 998(1-2), 73-82 (2003-07-17)
A series of chiral derivatizing reagents (CDRs) was synthesized by nucleophilic replacement of one chlorine atom in cyanuric chloride (2,4,6-trichloro-1,3,5-triazine; s-triazine) by alkoxy (methoxy, butoxy, 1,1,1-trifluoroethoxy) or aryloxy groups (phenoxy, nitrophenoxy, phenylphenoxy, 4-methylcoumaryloxy), and displacement of a second chlorine by
Tatsuki Nakano et al.
Analytica chimica acta, 880, 145-151 (2015-06-21)
In this study, a novel pre-column excimer fluorescence derivatization reagent, 2-chloro-4-methoxy-6-(4-(pyren-4-yl)butoxy)-1,3,5-triazine (CMPT), was developed for polyamines, specifically histamine. By CMPT derivatization, the polyamines, histamine and tyramine were converted to polypyrene derivatives, and emitted intra-molecular excimer fluorescence at 475nm. This could

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