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225959

Magnesium bromide ethyl etherate

99%

Synonym(s):

Dibromo(1,1′-oxybis(ethane))magnesium, Dibromo(diethyl ether)magnesium, Magnesium bromide diethyl etherate, Magnesium bromide etherate

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About This Item

Linear Formula:
MgBr2 · O(C2H5)2
CAS Number:
Molecular Weight:
258.23
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4937320
Assay:
99%
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Quality Level

assay

99%

reaction suitability

core: magnesium

functional group

ether

SMILES string

Br[Mg]Br.CCOCC

InChI

1S/C4H10O.2BrH.Mg/c1-3-5-4-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2

InChI key

JGZKUKYUQJUUNE-UHFFFAOYSA-L

Application

Magnesium bromide ethyl etherate can be used as a reagent:
  • In the Lewis acid-catalyzed Diels-Alder reactions.
  • For the conversion of aromatic aldehydes into alcohols and carboxylic acids via Cannizzaro reaction.


pictograms

Flame

signalword

Danger

hcodes

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Flam. Sol. 1 - Water-react. 2



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Tetrahedron Asymmetry, 2, 1193-1193 (1991)
Synthesis and Diels-Alder reactions of homochiral 2-sulfinylmaleates with cyclopentadiene
Alonso I, et al.
Tetrahedron Asymmetry, 2, 1193-1207 (1991)
Room-temperature Cannizzaro reaction under mild conditions facilitated by magnesium bromide ethyl etherate and triethylamine
Abaee M, et al.
Organic Letters, 7, 5893-5895 (2005)



Global Trade Item Number

SKUGTIN
225959-25G04061838779922
225959-100G04061833545386