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Chloro(1,5-cyclooctadiene)rhodium(I) dimer

greener alternative

98%

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Synonym(s):
1,5-Cyclooctadienerhodium(I) chloride dimer, Bis(1,5-cyclooctadiene)dirhodium(I) dichloride, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]dirhodium, Rhodium(I) chloride 1,5-Cyclooctadiene complex dimer, [Rh(COD)Cl]2
Empirical Formula (Hill Notation):
C16H24Cl2Rh2
CAS Number:
Molecular Weight:
493.08
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

98%

form

solid

reaction suitability

core: rhodium
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

mp

243 °C (dec.) (lit.)

greener alternative category

SMILES string

Cl[Rh].Cl[Rh].C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.2ClH.2Rh/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;

InChI key

QSUDXYGZLAJAQU-MIXQCLKLSA-L

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This Item
661023337331249939
reaction suitability

core: rhodium, reagent type: catalyst

reaction suitability

core: rhodium, reagent type: catalyst

reaction suitability

core: ruthenium, reaction type: solution phase peptide synthesis, reagent type: catalyst

reaction suitability

core: rhodium, reagent type: catalyst

form

solid

form

solid

form

-

form

powder

Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

100

mp

243 °C (dec.) (lit.)

mp

199 °C (dec.)

mp

-

mp

-

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Catalyst for coupling 1,3-dienes with activated hydrocarbons and for preparing chiral complexes.
Catalyst for oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Tetrahedron Asymmetry, 4, 2279-2279 (1993)
Pure and Applied Chemistry. Chimie Pure Et Appliquee, 66, 1509-1509 (1994)
Fung Kei Cheung et al.
Organic & biomolecular chemistry, 5(7), 1093-1103 (2007-03-23)
A series of catalysts have been prepared for use in the asymmetric transfer hydrogenation of ketones. The complexes were prepared using a [4 + 2] cycloaddition reaction at a key step in the reaction sequence. This provides a means for

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