247219

6-Bromo-1-hexene

95%

• Synonym(s): 1-Bromo-5-hexene, 5-Hexen-1-yl bromide, 5-Hexenyl bromide, 6-Bromohexene
• Linear Formula: Br(CH₂)₄CH=CH₂
• CAS Number: 2695-47-8
• Molecular Weight: 163.06
• Beilstein/REAXYS Number: 506203
• MDL number: MFCD00000269
• UNSPSC Code: 12352100
• PubChem Substance ID: 24854859
• NACRES: NA.22

Properties

• Quality Level: 200
• assay: 95%
• form: liquid
• impurities: <3% DMF
• refractive index: n20/D 1.465 (lit.)
• bp: 47-51 °C/16 mmHg (lit.)
• density: 1.22 g/mL at 25 °C (lit.)
• functional group: alkyl halide; allyl; bromo
• SMILES string: BrCCCCC=C
• InChI: 1S/C6H11Br/c1-2-3-4-5-6-7/h2H,1,3-6H2
• InChI key: RIMXEJYJXDBLIE-UHFFFAOYSA-N

Description

General description

Reaction of 6-bromo-1-hexene with Mg to form Grignard compounds has been investigated. The thermal chemistry of 6-bromo-1-hexene on Ni (100) surface has been studied under ultrahigh vacuum conditions by X-ray photoelectron spectroscopy and temperature-programmed desorption.

Application

6-Bromo-1-hexene was used in the preparation of epoxide, 6-bromo-1,2-epoxyhexane. It was also used in a simple, direct preparation of 4-alkenylbenzonitriles via anionic reduced forms of terephthalonitrile in liquid ammonia.

Safety Information

• pictograms: GHS02,GHS08,GHS07
• signalword: Danger
• hcodes: H226,H315,H319,H335,H360D
• pcodes: P202 - P210 - P233 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 129.2 °F - closed cup
• flash_point_c: 54 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter