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268607

Sigma-Aldrich

Formamidine hydrochloride

97%

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About This Item

Linear Formula:
HN=CHNH2 · HCl
CAS Number:
Molecular Weight:
80.52
Beilstein/REAXYS Number:
3906935
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

assay

97%

form

solid

mp

84-87 °C (lit.)

SMILES string

Cl[H].[H]C(N)=N

InChI

1S/CH4N2.ClH/c2-1-3;/h1H,(H3,2,3);1H

InChI key

NMVVJCLUYUWBSZ-UHFFFAOYSA-N

Application

Formamidine hydrochloride was used in the synthesis of imidazoleglycerol phosphate (IGP). It was also used in the synthesis of 5-methyl-4,6-dihydroxypyrimidine.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Reactions of oxidizing radicals with 4, 6-dihydroxypyrimidines as model compounds for uracil, thymine, and cytosine.
The Journal of Physical Chemistry, 91(2), 426-433 (1987)
Chung Hyeon Jang et al.
ACS nano, 14(10), 13246-13255 (2020-09-11)
A series of poly(fluorene-co-phenylene)-based anionic conjugated polyelectrolytes (CPEs) are prepared with varying sizes of counterions (tetramethylammonium, tetraethylammonium, and tetrabutylammonium (TBA+)) and studied as a hole-transporting layer (HTL) for sky-blue-emissive perovskite light-emitting diodes (PeLEDs). Ionic CPE HTLs improve the wettability, compatibility
The biosynthesis of histidine; D-erythro-imidazoleglycerol phosphate dehydrase.
B N AMES
The Journal of biological chemistry, 228(1), 131-143 (1957-09-01)
Federico Bertasi et al.
Physical chemistry chemical physics : PCCP, 19(38), 26230-26239 (2017-09-22)
This work describes the preparation of the new lipophilic ionic liquid tetraoctyl-formamidinium bis(trifluoromethanesulfonyl) imide (TOFATFSI), which is miscible with lower alkanes. In particular, this work focuses on the electric behaviour of TOFATFSI in the particularly challenging highly apolar environment of
Shulin Chen et al.
Organic letters, 13(23), 6152-6155 (2011-11-02)
A new N-sulfonyl formamidine synthesis was developed via NaI-catalyzed direct condensation of sulfonamide and formamide. The green methodology is featured by high atom economy, easily available starting materials, the lack of need for a transition-metal catalyst, no requirement of hazardous

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