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1-Ethyl-3-methylimidazolium chloride

98%

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Synonym(s):
EMIC
Empirical Formula (Hill Notation):
C6H11ClN2
CAS Number:
Molecular Weight:
146.62
Beilstein/REAXYS Number:
5163190
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

98%

form

solid

mp

77-79 °C (lit.)

SMILES string

[Cl-].CCn1cc[n+](C)c1

InChI

1S/C6H11N2.ClH/c1-3-8-5-4-7(2)6-8;/h4-6H,3H2,1-2H3;1H/q+1;/p-1

InChI key

BMQZYMYBQZGEEY-UHFFFAOYSA-M

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5648643961690597
Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

100

mp

77-79 °C (lit.)

mp

-

mp

-

mp

-

form

solid

form

-

form

crystals

form

liquid

General description

1-Ethyl-3-methylimidazolium chloride is an organic salt and a room-temperature ionic liquid (RTIL). It is used as a solvent in many organic reactions due to its unique properties like small vapor pressures, high thermal stabilities and ionic conductivities.

1-Ethyl-3-methylimidazolium chloride is an imidazolium-based ionic liquid used as a solvent in the Diels−Alder Reaction.

Application

EMIC may be used in the preparation of aluminum chloride-EMIC, zinc chloride-EMIC and EMIC /tetrafluoroborate molten salts, which are useful in electrodeposition studies.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

370.4 °F - closed cup

flash_point_c

188 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Elucidation of rate variations for a Diels- Alder reaction in ionic liquids from QM/MM simulations
Acevedo O, et al.
Journal of chemical theory and computation, 3(1), 132-138 (2007)
Carlos Rey-Castro et al.
The journal of physical chemistry. B, 110(29), 14426-14435 (2006-07-21)
We present here equilibrium molecular dynamics simulation results for self-diffusion coefficients, shear viscosity, and electrical conductivity in a model ionic liquid (1-ethyl-3-methylimidazolium chloride) at different temperatures. The Green-Kubo relations were employed to evaluate the transport coefficients. When compared with available
Electrodeposition of aluminum on magnesium alloy in aluminum chloride (AlCl 3)-1-ethyl-3-methylimidazolium chloride (EMIC) ionic liquid and its corrosion behavior.
Chang JK, et al.
Electrochemical Communications, 9(7), 1602-1606 (2007)
Lewis acidity dependency of the electrochemical window of zinc chloride-1-ethyl-3-methylimidazolium chloride ionic liquids.
Hsiu SI, et al.
Electrochimica Acta, 47(27), 4367-4372 (2002)
Anshu Sharma et al.
Carbohydrate polymers, 134, 617-626 (2015-10-03)
Ionic liquids (IL) can alter the physical properties of agar hydrogels. Rheology studies show that gels with wide range of storage moduli (gel strength) G0 values ranging from 1 to 20 KPa could be made in imidazolium based IL solutions

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