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275956

Sigma-Aldrich

Methyl p-tolyl sulfide

99%

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Synonym(s):
4-(Methylthio)toluene
Linear Formula:
CH3C6H4SCH3
CAS Number:
Molecular Weight:
138.23
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

99%

form

liquid

refractive index

n20/D 1.573 (lit.)

bp

52-54 °C/1 mmHg (lit.)

density

1.027 g/mL at 25 °C (lit.)

SMILES string

CSc1ccc(C)cc1

InChI

1S/C8H10S/c1-7-3-5-8(9-2)6-4-7/h3-6H,1-2H3

InChI key

VHILIAIEEYLJNA-UHFFFAOYSA-N

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This Item
158992253715343609
Methyl p-tolyl sulfide 99%

275956

Methyl p-tolyl sulfide

Methyl p-toluenesulfonate 98%

158992

Methyl p-toluenesulfonate

p-Tolyl isothiocyanate 97%

253715

p-Tolyl isothiocyanate

(R)-(+)-Methyl p-tolyl sulfoxide 99%

343609

(R)-(+)-Methyl p-tolyl sulfoxide

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

-

form

liquid

form

solid

form

solid

form

-

refractive index

n20/D 1.573 (lit.)

refractive index

n20/D 1.5172 (lit.)

refractive index

n20/D 1.6345 (lit.)

refractive index

-

bp

52-54 °C/1 mmHg (lit.)

bp

144-145 °C/5 mmHg (lit.)

bp

237 °C (lit.), 62 °C/0.3 mmHg (lit.)

bp

-

density

1.027 g/mL at 25 °C (lit.)

density

1.234 g/mL at 25 °C (lit.)

density

-

density

-

General description

Aerobic oxidation of methyl p-tolyl sulfide catalyzed by a heteroscorpionate Ru(II)-aqua complex has been reported. Chloroperoxidase catalyzed oxidation of methyl p-tolyl sulfide has been reported.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

185.0 °F - closed cup

flash_point_c

85 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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p-Tolyl disulfide 98%

Sigma-Aldrich

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Chloroperoxidase and hydrogen peroxide: An efficient system for enzymatic enantioselective sulfoxidations
Colonna S, et al.
Tetrahedron Asymmetry, 3(1), 95-106 (1992)
My Hang V Huynh et al.
Journal of the American Chemical Society, 125(2), 308-309 (2003-01-09)
fac-[RuII(Cl)(dpp)(L3)]+ (L3 = tris(pyrid-2-yl)methoxymethane (tpmm) = [1A]+ and tris(pyrid-2-yl)pentoxymethane (tppm) = [1B]+ and dpp = di(pyrazol-1-yl)propane) rapidly undergo ligand substitution with water to form fac-[RuII(H2O)(dpp)(L3)]2+ (L3 = tpmm = [2A]2+ and tppm = [2B]2+). In the structure of [2A]2+, the
Vasiliy Yu Evtushok et al.
Frontiers in chemistry, 7, 858-858 (2020-01-11)
In this work, we elaborated heterogeneous catalysts on the basis of the Venturello complex [PO4{WO(O2)2}4]3- (PW4) and nitrogen-free or nitrogen-doped carbon nanotubes (CNTs or N-CNTs) for epoxidation of alkenes and sulfoxidation of thioethers with aqueous hydrogen peroxide. Catalysts PW4/CNTs and

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