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Sigma-Aldrich

Manganese(II) nitrate hydrate

98%

Synonym(s):

Manganese(2+) dinitrate hydrate, Manganous dinitrate hydrate

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About This Item

Linear Formula:
Mn(NO3)2·xH2O
CAS Number:
Molecular Weight:
178.95 (anhydrous basis)
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

98%

form

solid

composition

Degree of hydration, 4-6

storage temp.

2-8°C

SMILES string

O.[Mn++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Mn.2NO3.H2O/c;2*2-1(3)4;/h;;;1H2/q+2;2*-1;

InChI key

HBTFASPVVFSRRI-UHFFFAOYSA-N

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General description

Manganese(II) nitrate hydrate is an inorganic salt highly soluble in water. It can be used as a source of manganese ions in the synthesis of various manganese-containing materials for batteries and supercapacitor applications. Additionally, it also serves as a safe, cost-effective, and efficient electrolyte for rapid energy storage applications.

Application

Manganese(II) nitrate hydrate can be used as:      
  • A precursor for the synthesis of manganese dioxide (MnO2), which is a common cathode material in primary alkaline batteries. 
  • A precursor in the synthesis of manganese dioxide (MnO2) for use in flexible micro supercapacitors. MnO2 exhibits high specific capacitance and excellent cycling stability, making it suitable for rapid energy storage applications.    
  • A manganese source in the colloidal solution combustion synthesis process to produce 3D δ-MnO2 nanostructures with ultra-large mesopores used in the fabrication of high-performance lithium-ion battery anodes.     
  • A precursor in the microwave-aided fabrication of calcium-substituted dysprosium perovskite manganite oxide nanocomposites (DyMnO3) for supercapacitor applications.

pictograms

Flame over circleExclamation mark

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Warning

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


Certificates of Analysis (COA)

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Separation of rare earths from transition metals by liquid-liquid extraction from a molten salt hydrate to an ionic liquid phase
Rout A and Binnemans K
Dalton Transactions, 43(8), 3186-3195 (2014)
Reactive ceramics of CeO2-MOx (M= Mn, Fe, Ni, Cu) for H2 generation by two-step water splitting using concentrated solar thermal energy
Kaneko H, et al.
Energy, 32(5), 656-663 (2007)
Jaechan Ryu et al.
Nature communications, 9(1), 3715-3715 (2018-09-15)
Aluminum-air batteries are promising candidates for next-generation high-energy-density storage, but the inherent limitations hinder their practical use. Here, we show that silver nanoparticle-mediated silver manganate nanoplates are a highly active and chemically stable catalyst for oxygen reduction in alkaline media.
Thermal characteristics of manganese (II) nitrate hexahydrate as a phase change material for cooling systems
Nagano K, et al.
Applied Thermal Engineering, 23(2), 229-241 (2003)
Breno R Barrioni et al.
Journal of colloid and interface science, 547, 382-392 (2019-04-12)
Bioactive glass nanoparticles (BGNPs) are of great interest in tissue engineering as they possess high dissolution rate and capability of being internalized by cells, releasing their dissolution products with therapeutic benefits intracellularly. A modified Stöber process can be applied to

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