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294713

Sigma-Aldrich

Aluminum chloride

99.99% trace metals basis

Synonym(s):

Aluminum trichloride

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About This Item

Linear Formula:
AlCl3
CAS Number:
7446-70-0
Molecular Weight:
133.34
EC Number:
231-208-1
MDL number:
MFCD00003422
UNSPSC Code:
12352302
eCl@ss:
38120507
PubChem Substance ID:
24857731
NACRES:
NA.23

vapor pressure

1 mmHg ( 100 °C)

Quality Level

200

assay

99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: aluminum

impurities

≤150.0 ppm Trace Metal Analysis

mp

190 °C (lit.)

SMILES string

Cl[Al](Cl)Cl

InChI

1S/Al.3ClH/h;3*1H/q+3;;;/p-3

InChI key

VSCWAEJMTAWNJL-UHFFFAOYSA-K

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General description

Aluminum chloride may be manufactured by chlorination of liquid aluminum in ceramic lined reaction vessels at 600-700oC.

Application

High strength steel has been coated electrochemically by Al in an acidic ionic liquid composed of 1-ethyl -3- methylimidazolium chloride and AlCl3. AlCl3 may be used to form Al-Cd alloy. Anhydrous alumunium chloride is a catalyst in organic chemistry especially for Friedel-Crafts reactions. It may also be used as a nucleation agent in the production of TiO2 pigment by the chloride process.

Features and Benefits

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resistance properties. Aluminum nitride can be synthesized from the elemnts with AlCl3 added to help facilitate crystallization.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH014,EUH071

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS8817
MKCT3370
MKCT0514
MKCS0987
MKCR0245

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Al-Cd Alloy Formation by Aluminum Underpotential Deposition from AlCl3+NaCl Melts on Cadmium Substrate
Niko Jovicevic, et al.
Metall. Mater. Trans. B, 44(1), 106-114 (2013)
Challenges in the electrochemical coating of high-strength steel screws by aluminum in an acidic ionic liquid composed of 1-Ethyl-3-methylimidazolium chloride and AlCl3
Sherif Zein El Abedin and Endres F
Journal of Solid State Electrochemistry, 17(4), 1127-1132 (2013)
Diagnosis and management of hyperhidrosis.
R A Benson et al.
BMJ (Clinical research ed.), 347, f6800-f6800 (2013-11-28)
Dharmalingam Prakash et al.
Neuromolecular medicine, 15(1), 192-208 (2013-01-15)
Aluminum (Al) is an environmental neurotoxin that affects cerebral functions and causes health complications. However, the role of Al in arbitrating glia homeostasis and pathophysiology remains obscure. Astrocyte, microglia activation (reactive gliosis), and associated inflammatory events play a decisive role
Bagineni Prasad et al.
Chemical communications (Cambridge, England), 48(84), 10434-10436 (2012-09-20)
A conceptually new and straightforward introduction of sulfonyl groups at the C-7 position of an indole ring has been achieved via AlCl(3) mediated unexpected regioselective sulfonyl group migration for N-alkyl/aryl/heteroarylsulfonyl indoles affording potential inhibitors of Mycobacterium tuberculosis H37Rv chorismate mutase.
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