All Photos(2)
α-Acetoxyacetic acid, (Acetyloxy)acetic acid, 2-(Acetyloxy)acetic acid, 2-Hydroxyacetic acid acetate, Acetylglycolic acid, O-Acetylglycolic acid
CH3CO2CH2CO2H
Recommended Products
Quality Level
assay
99%
bp
141-142 °C/12 mmHg (lit.)
mp
67-69 °C (lit.)
SMILES string
CC(=O)OCC(O)=O
InChI
1S/C4H6O4/c1-3(5)8-2-4(6)7/h2H2,1H3,(H,6,7)
InChI key
MLXDUYUQINCFFV-UHFFFAOYSA-N
Related Categories
General description
Acetoxyacetic acid is kinetically stable degradation product of oxidative degradation of 1,3-dialkylimidazolium ionic liquids in hydrogen peroxide/aceticacid aqueous medium assisted by ultrasonic chemical irradiation. It is an intermediate formed during reactions of manganic acetate in glacial acetic acid with benzene (100°C), chlorobenzene, or toluene.
Application
Acetoxyacetic acid was used in preparation of tert-butyl glycolate.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Certificates of Analysis (COA)
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Dalton transactions (Cambridge, England : 2003), (19)(19), 1875-1880 (2007-08-19)
A highly efficient process for oxidative degradation of 1,3-dialkylimidazolium ionic liquids in hydrogen peroxide/acetic acid aqueous medium assisted by ultrasonic chemical irradiation is, for the first time, described. It is shown that more than 93% of the 1,3-dialkylimidazolium cation with
Intermediate steps in autoxidation: III. Reactions of MnIII acetate in acetic acid with benzene, chlorobenzene, and toluene.
J. Catal., 10(1), 52-59 (1968)
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