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303828

Sigma-Aldrich

Ethylmagnesium chloride solution

2.0 M in THF

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Synonym(s):
Chloroethylmagnesium
Linear Formula:
CH3CH2MgCl
CAS Number:
Molecular Weight:
88.82
Beilstein/REAXYS Number:
3647886
MDL number:
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

reaction suitability

reaction type: Grignard Reaction

concentration

2.0 M in THF

density

0.978 g/mL at 25 °C

SMILES string

CC[Mg]Cl

InChI

1S/C2H5.ClH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1

InChI key

ZWNJJACKPNTXHY-UHFFFAOYSA-M

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Ethylmagnesium chloride solution 2.0 M in THF

303828

Ethylmagnesium chloride solution

Methylmagnesium chloride solution 3.0 M in THF

189901

Methylmagnesium chloride solution

Phenylmagnesium chloride solution 2.0 M in THF

224448

Phenylmagnesium chloride solution

Octylmagnesium chloride solution 2.0 M in THF

324566

Octylmagnesium chloride solution

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

form

liquid

form

-

form

-

form

-

density

0.978 g/mL at 25 °C

density

1.013 g/mL at 25 °C

density

~1.02 g/mL at 20 °C, 1.042 g/mL at 25 °C

density

0.929 g/mL at 25 °C

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

Application

Ethylmagnesium chloride solution can be used:
  • In Cp2ZrCl2 catalyzed ethylcarboxylation of alkenes using carbon dioxide to corresponding carboxylic acids.
  • In the preparation of cyclobutylmagnesium carbenoids by reacting with 1-chlorocyclobutyl p-tolyl sulfoxides.

signalword

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1

supp_hazards

Storage Class

4.3 - Hazardous materials, which set free flammable gases upon contact with water

wgk_germany

WGK 1

flash_point_f

1.4 °F - closed cup

flash_point_c

-17 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Customers Also Viewed

Cyclobutylmagnesium Carbenoids: Generation from 1-Chlorocyclobutyl p-Tolyl Sulfoxides with Ethylmagnesium Chloride, Properties, and Some Synthetic Uses
Satoh T, et al.
Synlett, 2010(02), 286-290 (2010)
Zirconocene-catalyzed sequential ethylcarboxylation of alkenes using ethylmagnesium chloride and carbon dioxide
Shao P, et al.
Chemical Communications (Cambridge, England), 51(30), 6640-6642 (2015)

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