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375071

Sigma-Aldrich

Bisphenol A bis(chloroformate)

95%

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Linear Formula:
(ClCO2C6H4)2C(CH3)2
CAS Number:
2024-88-6
Molecular Weight:
353.20
EC Number:
217-970-8
MDL number:
MFCD00060109
UNSPSC Code:
12352100
PubChem Substance ID:
24863362
NACRES:
NA.22

Quality Level

100

assay

95%

mp

90-92 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(C)(c1ccc(OC(Cl)=O)cc1)c2ccc(OC(Cl)=O)cc2

InChI

1S/C17H14Cl2O4/c1-17(2,11-3-7-13(8-4-11)22-15(18)20)12-5-9-14(10-6-12)23-16(19)21/h3-10H,1-2H3

InChI key

MMWCQWOKHLEYSP-UHFFFAOYSA-N

Related Categories

General description

Bisphenol A (BPA) is reported as an environmental endocrine disrupting chemical that affects reproduction in wildlife. BPA is a monomer of polycarbonate plastics and forms an important constituent of epoxy and polystyrene resins, used in the food packing industry. Effect of bisphenol A bis(chloroformate) on conversion of 3T3-L1 fibroblasts to adipocytes is reported.

Application

Bisphenol A bis(chloroformate) is suitable for use in the synthesis of poly(carbonates) derived from diphenols that contain Si or Ge. It may be used:
  • in the preparation of novel electro-optic (EO) polycarbonates containing two different kinds of nonlinear optical (NLO) chromophores with tricyanofurane (TCF) electron acceptor
  • in the preparation of novel fluorine-containing poly(carbonate-block-siloxanes)
  • as coupling reagent in the synthesis of block-copolymers containing poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and polycarbonate of bisphenol A (PC) segments

Pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Fluorine-containing poly (carbonate-block-siloxane) copolymers.
Anashkin DO, et al.
Polymer Science, Series A, 51(13), 2841-2849 (2013)
Synthesis and characterization of poly (carbonates) derived from diphenols that contain silicon or germanium.
Tagle LH, et al.
Journal of Inorganic and Organometallic Polymers and Materials, 13(1), 21-28 (2003)
Hiroshi Masuno et al.
Journal of lipid research, 43(5), 676-684 (2002-04-25)
The confluent cultures of 3T3-L1 fibroblasts were treated with or without bisphenol A (BPA) for 2 days and subsequently treated with insulin (INS) alone for 9 days. When BPA was absent during the first 2-day treatment period, the cultures contained
Facile synthesis and electro-optic activities of new polycarbonates containing tricyanofuran-based nonlinear optical chromophores.
Deng G, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 51(13), 2841-2849 (2013)
PPO-PC block-copolymers used as compatibilizers in PS/PC blends.
Sartore L, et al.
Journal of Applied Polymer Science, 100(6), 4654- 4660 (2006)

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