376345

(1S,3R)-(−)-Camphoric acid

99%

• Synonym(s): (−)-Camphoric acid, (1S,3R)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
• Empirical Formula (Hill Notation): C₁₀H₁₆O₄
• CAS Number: 560-09-8
• Molecular Weight: 200.23
• Beilstein/REAXYS Number: 1874674
• MDL number: MFCD00064937
• UNSPSC Code: 51113400
• PubChem Substance ID: 24863434
• NACRES: NA.22

Properties

• assay: 99%
• optical activity: [α]20/D −48°, c = 10 in ethanol
• mp: 188-190 °C (lit.)
• SMILES string: CC1(C)[C@@H](CC[C@]1(C)C(O)=O)C(O)=O
• InChI: 1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m0/s1
• InChI key: LSPHULWDVZXLIL-QUBYGPBYSA-N

Description

Application

(1S,3R)-(−)-Camphoric acid can be used:

• As an enantiomeric linker in the preparation of chiral surface-anchored metal-organic frameworks (MOFs).
• To prepare porous MOFs having multifunctional properties; used in gas adsorption and separation of racemic alcohols.
• To prepare a cobalt(II) coordination polymer named {Co(phen)(H₂O)[C₈H₁₄(COO)₂]}_n·(CH₃OH)_n , wherein “phen” is 1,10-phenanthroline and C₈H₁₄(COOH)₂ is [(1S,3R)-camphoric acid.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)