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Sigma-Aldrich

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide

≥98.0% (T)

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Synonym(s):
BMP-BTI
Empirical Formula (Hill Notation):
C11H20F6N2O4S2
CAS Number:
Molecular Weight:
422.41
MDL number:
PubChem Substance ID:
NACRES:
NA.22

description

electrochemical window -3.0 - +2.4 V

Quality Level

assay

≥98.0% (T)

impurities

≤0.2% water

viscosity

548 stokes

mp

-18 °C

SMILES string

CCCC[N+]1(C)CCCC1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C9H20N.C2F6NO4S2/c1-3-4-7-10(2)8-5-6-9-10;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3-9H2,1-2H3;/q+1;-1

InChI key

HSLXOARVFIWOQF-UHFFFAOYSA-N

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1 of 4

This Item
40963900873713155
Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

-18 °C

mp

-18 °C

mp

-18 °C

mp

-

description

electrochemical window -3.0 - +2.4 V

description

-

description

-

description

-

impurities

≤0.2% water

impurities

≤400 ppm water

impurities

<500 ppm H2O

impurities

≤0.5% water

viscosity

548 stokes

viscosity

-

viscosity

-

viscosity

-

General description

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide is a room temperature ionic liquid (RTIL) with a wide electrochemical window (5.5V) and high viscosity, making it a useful candidate in electrochemical energy applications.

Application

BMP-BTI has been used as a derivatization media for dimethyl sulfate (DMS) with dibenzazepine.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Electrochemical study of copper chloride complexes in the RTIL 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
Vainikka, Tuomas, et al.
Electrochimica Acta, 87, 739-748 (2013)
Electrochemical behavior of oxygen/superoxide ion couple in 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide room-temperature molten salt
Katayama, Yasushi, et al.
Journal of the Electrochemical Society, 152.8, E247-E250 (2005)
Aluminium Speciation in 1?Butyl?1?Methylpyrrolidinium Bis (trifluoromethylsulfonyl) amide/AlCl3 Mixtures
Rocher, Nathalie M., et al.
Chemistry?A European Journal , 15.14, 3435-3447 (2009)
Novel amperometric sensors for nitrite detection using electrodes modified with PEDOT prepared in ionic liquids
Gligor, Delia, et al.
Journal of Solid State Electrochemistry, 21.1, 281-290 (2017)
Physicochemical characterization of 1-butyl-3-methylimidazolium and 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) imide
Vranes, Milan, et al.
Journal of Chemical and Engineering Data, 57.4, 1072-1077 (2012)

Articles

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

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