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Sigma-Aldrich

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide

≥98.0% (T)

Synonym(s):

BMP-BTI

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About This Item

Empirical Formula (Hill Notation):
C11H20F6N2O4S2
CAS Number:
223437-11-4
Molecular Weight:
422.41
MDL number:
MFCD07784447
UNSPSC Code:
12352100
PubChem Substance ID:
57649870
NACRES:
NA.22

description

electrochemical window -3.0 - +2.4 V

assay

≥98.0% (T)

impurities

≤0.2% water

viscosity

548 stokes

mp

-18 °C

functional group

fluoro

SMILES string

CCCC[N+]1(C)CCCC1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C9H20N.C2F6NO4S2/c1-3-4-7-10(2)8-5-6-9-10;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3-9H2,1-2H3;/q+1;-1

Inchi Key

HSLXOARVFIWOQF-UHFFFAOYSA-N

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General description

1-Butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide is a room temperature ionic liquid (RTIL) with a wide electrochemical window (5.5V) and high viscosity, making it a useful candidate in electrochemical energy applications.

Application

BMP-BTI has been used as a derivatization media for dimethyl sulfate (DMS) with dibenzazepine.

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCM6003
BCCJ6753
BCCK9979
BCCC1255
BCCH0712

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Ionic Liquids for Energy Storage Applications
Stenger-Smith JD and Irvin JA.
Material Matters, 4(4), 103-103 (2009)
Electrodeposition of al in 1-butyl-1-methylpyrrolidinium bis (trifluoromethylsulfonyl) amide and 1-ethyl-3-methylimidazolium bis (trifluoromethylsulfonyl) amide ionic liquids: In situ STM and EQCM studies
Moustafa, E. M., et al.
The Journal of Physical Chemistry B, 111.18, 4693-4704 (2007)
Electrochemical reduction of O 2 in 1-butyl-1-methylpyrrolidinium bis (trifluoromethanesulfonyl) imide ionic liquid containing Zn 2+ cations: deposition of non-polar oriented ZnO nanocrystalline films
Azaceta, Eneko, et al.
Physical Chemistry Chemical Physics, 13.29, 13433-13440 (2011)
An ionic liquid based strain sensor for large displacement measurement
Keulemans, Grim, Frederik Ceyssens, and Robert Puers
Biomedical Microdevices, 19.1, 1-1 (2017)
Additive free electrodeposition of nanocrystalline aluminium in a water and air stable ionic liquid
El Abedin, S. Zein, et al.
Electrochemical Communications, 7.11, 1111-1116 (2005)
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Articles

Ionic Liquids for Energy Storage Applications

Ionic liquids, also called room temperature ionic liquids, are organic salts that are liquid at, or close to, room temperature.

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