395005

N,N-Dimethylformamide di-tert-butyl acetal

for GC derivatization, LiChropur^™

• Synonym(s): 1,1-Di-tert-butoxy-N,N-dimethylmethylamine, 1,1-Di-tert-butoxytrimethylamine
• Linear Formula: (CH₃)₂NCH[OC(CH₃)₃]₂
• CAS Number: 36805-97-7
• Molecular Weight: 203.32
• Beilstein/REAXYS Number: 969629
• EC Number: 253-222-7
• MDL number: MFCD00015002
• UNSPSC Code: 12000000
• PubChem Substance ID: 24864634
• NACRES: NA.22

Properties

• grade: for GC derivatization
• Quality Level: 100
• assay: ≥90.0%
• form: liquid
• quality: LiChropur^™
• reaction suitability: reagent type: derivatization reagent; reaction type: Acylations
• technique(s): gas chromatography (GC): suitable
• refractive index: n20/D 1.413 (lit.)
• bp: 56-57 °C/8 mmHg (lit.)
• density: 0.848 g/mL at 25 °C (lit.)
• SMILES string: CN(C)C(OC(C)(C)C)OC(C)(C)C
• InChI: 1S/C11H25NO2/c1-10(2,3)13-9(12(7)8)14-11(4,5)6/h9H,1-8H3
• InChI key: DBNQIOANXZVWIP-UHFFFAOYSA-N

Description

General description

N,N-Dimethylformamide di-tert-butyl acetal is an derivatizing reagent.

Application

It was used as derivatizing agent in a study to determine cocaine and benzoyl ecgonine in urine using GC with on-column alkylation.

Reagent used for the preparation of indolizines via intermolecular cyclization of picolinium salts.

Packaging

Clear borosilicate glass, high hydrolytic resistance (Type I)

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• pictograms: GHS02,GHS07
• signalword: Warning
• hcodes: H226,H315,H319,H335
• pcodes: P210 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 95.0 °F - closed cup
• flash_point_c: 35 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter