395439
Chloro(dimethyl)vinylsilane
97%
Synonym(s):
Dimethylvinylchlorosilane, Vinyldimethylchlorosilane
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About This Item
Linear Formula:
H2C=CHSi(CH3)2Cl
CAS Number:
Molecular Weight:
120.65
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-007-1
Beilstein/REAXYS Number:
1737688
MDL number:
Assay:
97%
Form:
liquid
InChI key
XSDCTSITJJJDPY-UHFFFAOYSA-N
InChI
1S/C4H9ClSi/c1-4-6(2,3)5/h4H,1H2,2-3H3
SMILES string
C[Si](C)(Cl)C=C
assay
97%
form
liquid
Quality Level
bp
82-83 °C (lit.)
density
0.874 g/mL at 25 °C (lit.)
Related Categories
General description
Chloro(dimethyl)vinylsilane (Dimethylvinylchlorosilane, Vinyldimethylchlorosilane, C4H9ClSi) is an organosilicon compound. It participates in the preparation of 1,1,2,2-tetramethyl-1,2-divinyldisilane. It undergoes [2+4] cycloaddition reaction with t-butyllithium in the presence of 2,3-dimethyl-1,3-butadiene to afford cycloadducts.
Application
Chloro(dimethyl)vinylsilane may be used in the synthesis of dimethyl(prop-2-ynyloxy)(vinyl)silane.
Chloro(dimethyl)vinylsilane may be used to prepare silicon-containing polymers, silaheterocycles, and new chelating ligands.
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Danger
hcodes
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
23.0 °F - closed cup
flash_point_c
-5 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Zeitschrift fur Anorganische und Allgemeine Chemie, 608, 43-43 (1992)
Vinylmetalloids: I. Coupling reactions of group IV metalloidal halides with magnesium in tetrahydrofuran.
Soderquist JA and Hassner A
Journal of Organometallic Chemistry, 156(1), 227-233 (1978)
The Journal of Organic Chemistry, 57, 5279-5279 (1992)
Schertzer BM.
The Development of Tandem Reactions Involving Enyne Metathesis to Form Substituted Cyclic Dienes, 209-209 (2006)
Katritzky AR, et al.
Comprehensive Organic Functional Group Transformations: Synthesis: carbon with two heteroatoms, each attached by a single bond, 4, 611-611 (1995)
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