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496375

Sigma-Aldrich

4′-(4-Methylphenyl)-2,2′:6′,2′′-terpyridine

98%

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Empirical Formula (Hill Notation):
C22H17N3
CAS Number:
89972-77-0
Molecular Weight:
323.39
MDL number:
MFCD06796977
PubChem Substance ID:
24873051
NACRES:
NA.22

Quality Level

100

Assay

98%

mp

167-170 °C (lit.)

SMILES string

Cc1ccc(cc1)-c2cc(nc(c2)-c3ccccn3)-c4ccccn4

InChI

1S/C22H17N3/c1-16-8-10-17(11-9-16)18-14-21(19-6-2-4-12-23-19)25-22(15-18)20-7-3-5-13-24-20/h2-15H,1H3

InChI key

IDJYBUVHZHLIIT-UHFFFAOYSA-N

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1 of 4

This Item
234672494070690163
4′-(4-Methylphenyl)-2,2′:6′,2′′-terpyridine 98%

Sigma-Aldrich

496375

4′-(4-Methylphenyl)-2,2′:6′,2′′-terpyridine

2,2′:6′,2′′-Terpyridine 98%

Sigma-Aldrich

234672

2,2′:6′,2′′-Terpyridine

6,6′′-Dibromo-2,2′:6′,2′′-terpyridine 90%

Sigma-Aldrich

494070

6,6′′-Dibromo-2,2′:6′,2′′-terpyridine

Trimethyl 2,2′:6′,2″-terpyridine-4,4′,4″-tricarboxylate 98%

Sigma-Aldrich

690163

Trimethyl 2,2′:6′,2″-terpyridine-4,4′,4″-tricarboxylate

mp

167-170 °C (lit.)

mp

89-91 °C (lit.)

mp

257-263 °C (lit.)

mp

-

General description

4′-(4-Methylphenyl)-2,2′:6′,2′′-terpyridine is a tridentate oligopyridine ligand. Its crystalline structure has been investigated.

Application

4′-(4-Methylphenyl)-2,2′:6′,2′′-terpyridine may be used as a ligand in the synthesis of:
  • terpyridine Ru(II) complexes
  • terpyridine based Cd(II) and Hg(II) complexes
  • heterobimetallic Ru(II)-Os(II) complexes

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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4'-(4-Methylphenyl)-2,2':6',2''-terpyridine.
Liu HG, et al.
Acta Crystallographica Section E, Structure Reports Online, 63(12), o4876-o4876 (2007)
Photoinduced intramolecular energy transfer and anion sensing studies of isomeric RuII OsII complexes derived from an asymmetric phenanthroline-terpyridine bridge.
Maity D, et al.
Dalton Transactions, 43(4), 1829-1845 (2014)
K Yamamoto et al.
Life sciences, 59(25-26), 2139-2146 (1996-01-01)
We have identified 4'-(4-methylphenyl)-2,2':6',2-terpyridine: trihydrochloride (SS701), which belongs to a family of a small unique neuroprotective agents. SS701 accelerated the production of nerve growth factor (NGF) in cultured astroglial cells, dose- and time-dependently. In in vivo studies, SS701, when administered
Synthesis, crystal structure and thermal properties of Cd(II) and Hg(II) terpyridine based compounds.
Saghatforoush L, et al.
Main Group Chemistry, 13(1), 29-39 (2014)
Li Jiao Liang et al.
The Analyst, 137(4), 953-958 (2011-12-21)
Pyrophosphate ion (PPi) is crucial in varieties of biological processes and industrial applications, and thus it is very important how to recognize it with high selectivity. In this contribution, one terpyridine (tpy)-based fluorescent molecule, 4-(methylphenyl)-2,2':6',2''-terpyridine (mptpy), has been reported to
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