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516775

Sigma-Aldrich

3-Bromo-4-hydroxybenzaldehyde

97%

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About This Item

Linear Formula:
BrC6H3(OH)CHO
CAS Number:
Molecular Weight:
201.02
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

mp

130-135 °C (lit.)

SMILES string

Oc1ccc(C=O)cc1Br

InChI

1S/C7H5BrO2/c8-6-3-5(4-9)1-2-7(6)10/h1-4,10H

InChI key

UOTMHAOCAJROQF-UHFFFAOYSA-N

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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Formation of 3-bromo-4-hydroxybenzaldehyde from L-tyrosine in cell-free homogenates of Odonthalia floccosa (Rhodophyceae): a proposed biosynthetic pathway for brominated phenols.
Manley SL and Chapman DJ.
Febs Letters, 93(1), 97-101 (1978)
C Flodin et al.
Phytochemistry, 53(1), 77-80 (2000-02-03)
The red marine alga Polysiphonia sphaerocarpa was extracted by a simultaneous steam distillation-solvent extraction technique and several brominated compounds were identified by gas chromatography-mass spectrometry. The compounds detected were 2,4-dibromoanisole, 2,4,6-tribromoanisole, 3-bromocresol, 3,5-dibromocresol, 3-bromo-4-hydroxybenzaldehyde, 3,5-dibromo-4-hydroxybenzaldehyde, 2-bromophenol, 4-bromophenol, 2,4-dibromophenol, 2,6-dibromophenol and
Hard acid and soft nucleophile system. New efficient method for removal of benzyl protecting group.
Fuji K, et al.
The Journal of Organic Chemistry, 44(10), 1661-1664 (1979)
S L Manley et al.
Plant physiology, 64(6), 1032-1038 (1979-12-01)
The biosynthesis of 4-hydroxybenzaldehyde and 3-bromo-4-hydroxybenzaldehyde from l-[U-(14)C]tyrosine has been demonstrated in chloroplast-containing fractions obtained by differential and isopycnic centrifugation from the marine red alga Odonthalia floccosa. Surfactant and high speed centrifugation studies indicate that the biosynthetic pathway involves a
Eun-Hye Kim et al.
Journal of materials chemistry. B, 8(44), 10162-10171 (2020-10-24)
Monoclonal antibodies have been developed as anticancer agents to block immune checkpoint pathways associated with programmed cell death 1 (PD-1) and its ligand PD-L1. However, the high cost of antibodies has encouraged researchers to develop other inhibitor types. Here, biphenyl

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