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646075

Sigma-Aldrich

p-Tolylmagnesium bromide solution

0.5 M in diethyl ether

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Synonym(s):
4-Methylphenylmagnesium bromide
Linear Formula:
CH3C6H4MgBr
CAS Number:
Molecular Weight:
195.34
Beilstein/REAXYS Number:
636491
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in diethyl ether

SMILES string

Cc1ccc([Mg]Br)cc1

InChI

1S/C7H7.BrH.Mg/c1-7-5-3-2-4-6-7;;/h3-6H,1H3;1H;/q;;+1/p-1

InChI key

ZRJNGFJIBZKXTP-UHFFFAOYSA-M

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1 of 4

This Item
442178298980332402
p-Tolylmagnesium bromide solution 0.5 M in diethyl ether

646075

p-Tolylmagnesium bromide solution

p-Tolylmagnesium bromide solution 1.0 M in THF

442178

p-Tolylmagnesium bromide solution

o-Tolylmagnesium bromide solution 2.0 M in diethyl ether

298980

o-Tolylmagnesium bromide solution

concentration

0.5 M in diethyl ether

concentration

1.0 M in THF

concentration

2.0 M in diethyl ether

concentration

1.0 M in diethyl ether

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system

supp_hazards

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-40.0 °F - closed cup - Solvent

flash_point_c

-40 °C - closed cup - Solvent

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Derek E Williams et al.
Journal of the American Chemical Society, 140(24), 7611-7622 (2018-05-29)
Stimuli-responsive materials are vital for addressing emerging demands in the advanced technology sector as well as current industrial challenges. Here, we report for the first time that coordinative integration of photoresponsive building blocks possessing photochromic spiropyran and diarylethene moieties within
Ekaterina A Dolgopolova et al.
Journal of the American Chemical Society, 141(13), 5350-5358 (2019-03-07)
Electronic structure modulation of metal-organic frameworks (MOFs) through the connection of linker "wires" as a function of an external stimulus is reported for the first time. The established correlation between MOF electronic properties and photoisomerization kinetics as well as changes

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