688495
(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline
97%
Synonym(s):
(4S)-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-4,5-dihydrooxazole
About This Item
Recommended Products
Quality Level
assay
97%
form
solid
optical activity
[α]22/D -57.0°, c = 1 in chloroform
mp
111-116 °C
storage temp.
−20°C
SMILES string
CC(C)(C)[C@@H]1N=C(C2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4)OC1
InChI
1S/C25H26NOP/c1-25(2,3)23-18-27-24(26-23)21-16-10-11-17-22(21)28(19-12-6-4-7-13-19)20-14-8-5-9-15-20/h4-17,23H,18H2,1-3H3/t23-/m1/s1
InChI key
DMOLTNKQLUAXPI-HSZRJFAPSA-N
Related Categories
General description
Application
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Certificates of Analysis (COA)
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Articles
Modular P,N-ligands in asymmetric synthesis introduced by Pfaltz, Helmchen, and Williams exhibit success in metal-catalyzed reactions.
Related Content
Andreas Pfaltz has a longstanding interest in the design of chiral ligands for asymmetric catalysis. The semicorrins developed in his group served as the prototype for an important family of nitrogen ligands, the bisoxazolines, which have found widespread use in catalytic asymmetric synthesis.
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