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Sigma-Aldrich

Magnesium monoperoxyphthalate hexahydrate

technical, ~80% (RT)

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Synonym(s):
Magnesium bis(monoperoxyphthalate) hexahydrate, MMPP
Linear Formula:
(HO2CC6H4CO3)2Mg·6H2O
Molecular Weight:
494.64
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

grade

technical

Assay

~80% (RT)

form

powder

reaction suitability

reagent type: oxidant

mp

93 °C (dec.) (lit.)

SMILES string

O.O.O.O.O.O.OOC(=O)c1ccccc1C(=O)O[Mg]OC(=O)c2ccccc2C(=O)OO

InChI

1S/2C8H6O5.Mg.6H2O/c2*9-7(10)5-3-1-2-4-6(5)8(11)13-12;;;;;;;/h2*1-4,12H,(H,9,10);;6*1H2/q;;+2;;;;;;/p-2

InChI key

WWOYCMCZTZTIGU-UHFFFAOYSA-L

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This Item
283207M0250M1880
form

powder

form

-

form

solid

form

powder or crystals

reaction suitability

reagent type: oxidant

reaction suitability

reagent type: oxidant

reaction suitability

-

reaction suitability

-

mp

93 °C (dec.) (lit.)

mp

93 °C (dec.) (lit.)

mp

-

mp

-

grade

technical

grade

-

grade

-

grade

-

General description

Magnesium monoperoxyphthalate hexahydrate is an organic peroxide used in many oxidation reactions. It exhibits non-deflagrating and non-shock-sensitive properties and also used as a surface disinfectant.

Application

Reagent for:
  • Trans-diaxial hydroxylation under bismuth(III) triflate catalyst
  • Oxidation rections under mild conditions
  • Epoxidation of unsaturated steroids
  • Synthesis of ring-B oxygenated steroids as anticancer agents

Other Notes

Versatile oxidant soluble in water and the lower alcohols.; Oxidations are carried out in homogenous solution (alcohol, aqueous alcohol) or in a two-phase system under PTC (chloroform-water)

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Dam. 1 - Org. Perox. E - Skin Corr. 1C

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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25G
Pack Size/Quantity

Additional examples:

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

enter as 1.000309185)

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Novel organic peroxygen reagents for use in organic synthesis
Organic peroxygen chemistry, 1-19 (1993)
D. Enders et al.
Synlett, 725-725 (1990)
F. Fringuelli et al.
The Journal of Organic Chemistry, 57, 1198-1198 (1992)
Efficacy of three surface disinfectants against spores of Clostridium difficile ribotype 027
Horejsh D and Kampf G
International Journal of Hygiene and Environmental Health, 214(2), 172-174 (2011)
P. Brougham et al.
Synthesis, 1015-1015 (1987)

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