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723142

Sigma-Aldrich

Tris[2-(dimethylamino)ethyl]amine

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Synonym(s):
Me6TREN
Empirical Formula (Hill Notation):
C12H30N4
CAS Number:
Molecular Weight:
230.39
MDL number:
PubChem Substance ID:
NACRES:
NA.23

assay

97%

form

liquid

refractive index

n20/D 1.455

density

0.862 g/mL at 25 °C

SMILES string

CN(C)CCN(CCN(C)C)CCN(C)C

InChI

1S/C12H30N4/c1-13(2)7-10-16(11-8-14(3)4)12-9-15(5)6/h7-12H2,1-6H3

InChI key

VMGSQCIDWAUGLQ-UHFFFAOYSA-N

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This Item
22563025318939380
vibrant-m

723142

Tris[2-(dimethylamino)ethyl]amine

vibrant-m

225630

Tris(2-aminoethyl)amine

vibrant-m

253189

Tris(diethylamino)phosphine

vibrant-m

39380

3-(Dimethylamino)-1-propylamine

density

0.862 g/mL at 25 °C

density

0.976 g/mL at 20 °C (lit.)

density

0.903 g/mL at 25 °C (lit.)

density

0.812 g/mL at 25 °C (lit.)

refractive index

n20/D 1.455

refractive index

n20/D 1.497 (lit.)

refractive index

n20/D 1.475 (lit.)

refractive index

n20/D 1.435 (lit.), n20/D 1.436

form

liquid

form

liquid

form

liquid

form

liquid

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

General description

Tris[2-(dimethylamino)ethyl]amine (Me6TREN) is an aliphatic tertiary amine that forms a quadridentate ligand. It is majorly used in atom transfer radical polymerization (ATRP). It is a hexamethyl derivative of (2-aminoethyl)amine, also known as trenMe. It can be prepared by a modification of Ristempart′s synthesis.

Application

Atom Transfer Radical Polymerization (ATRP) ligand for the creation of telechelic polymers.
Me6TREN forms a complex with copper compounds which can potentially be used as ligands in metalloenzyme redox reactions.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

219.9 °F - closed cup

flash_point_c

104.4 °C - closed cup


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Articles

Atom transfer radical polymerization (ATRP) has emerged as one of the most successful synthetic techniques for the preparation of polymers with predetermined molecular weights, narrow molecular weight distributions, and high degrees of chain end functionalities.

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Protocols

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

An article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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